Department Atomic-Scale Dynamics in Light-Energy Conversion
Publications
2023
60. Reversible and Irreversible Cation Intercalation in NiFeOx Oxygen Evolution Catalysts in Alkaline Media
Hanna Trzesniowski, Nipon Deka, Onno van der Heijden, Ronny Golnak, Jie Xiao, Marc T. M. Koper, Robert Seidel, and Rik V. Mom
The Journal of Physical Chemistry Letters 2023, 14, 2, 545–551 DOI: 10.1021/acs.jpclett.2c03336
2022
59. Understanding X-ray Photoelectron Spectra of Ionic Liquids: Experiments and Simulations of 1-Butyl-3-methylimidazolium Thiocyanate
Ekaterina Gousseva, Scott D. Midgley, Jake M. Seymour, Robert Seidel, Ricardo Grau-Crespo, and Kevin R. J. Lovelock
The Journal of Physical Chemistry B 2022, 126 (49), 10500-10509 DOI: 10.1021/acs.jpcb.2c06372
58. Dip-and-pull ambient pressure photoelectron spectroscopy as a spectroelectrochemistry tool for probing molecular redox processes
Robert H. Temperton, Anurag Kawde, Axl Eriksson, Weijia Wang, Esko Kokkonen, Rosemary Jones, Sabrina Maria Gericke, Suyun Zhu, Wilson Quevedo, Robert Seidel, Joachim Schnadt, Andrey Shavorskiy, Petter Persson, and Jens Uhlig
Journal of Chemical Physics 2022, 157, 244701 DOI: 10.1063/5.0130222
57. Resonant X-ray photoelectron spectroscopy: identification of atomic contributions to valence states
Jake M. Seymour, E. Gousseva, R. A. Bennett, A. O. Large, G. Held, Dennis Hein, Garlef Wartner, Wilson Quevedo, Robert Seidel, Claudia Kolbeck, C. J. Clarke, R. M. Fogarty, R. A. Bourne, R. G. Palgrave, Patricia A. Hunt, and Kevin R. J. Lovelock
Faraday Discussion 2022, 236, 389-411 DOI: 10.1039/D1FD00117E
56. Observation of intermolecular Coulombic decay and shake-up satellites in liquid ammonia
Hanns Christian Schewe, Eva Muchová, Michal Belina, Tillmann Buttersack, Dominik Stemer, Robert Seidel, Stephan Thürmer, Petr Slavíček, and Bernd Winter
Structural Dynamics 2022, 9, 044901 DOI: 10.1063/4.0000151
55. Accessing the solid electrolyte interphase on silicon anodes for lithium-ion batteries in-situ through transmission soft X-ray absorption spectroscopy
Martin Schellenberger, Ronny Golnak, Wilson G. Quevedo Garzon, Sebastian Risse, and Robert Seidel;
Material Today Advances 2022, 14, 100215 DOI: 10.1016/j.mtadv.2022.100215
54. Photoelectron angular distributions as sensitive probes of surfactant layer structure at the liquid-vapor interface
Rémi Dupuy, Jakob Filser, Clemens Richter, Robert Seidel, Florian Trinter, Tillmann Buttersack, Christophe Nicolas, John Bozek, Uwe Hergenhahn, Harald Oberhofer, Bernd Winter, Karsten Reuter, and Hendrik Bluhm;
Physical Chemistry Chemical Physics 2022, 24 (8), 4796-4808 DOI: 10.1039/d1cp05621b
53. Photoelectron Spectroscopy of Benzene in the Liquid Phase and Dissolved in Liquid Ammonia
H. Christian Schewe, Krystof Brezina, Vojtech Kostal, Philip E. Mason, Tillmann Buttersack, Dominik M. Stemer, Robert Seidel, Wilson Quevedo, Florian Trinter, Bernd Winter, and Pavel Jungwirth;
The Journal of Physical Chemistry B 2022, 126, 229-238 DOI: 10.1021/acs.jpcb.1c08172
2021
52. Following in Emil Fischer’s footsteps: a site-selective probe of glucose acid-base chemistry
Sebastian Malerz, Karen Mudryk, Lukáš Tomaník, Dominik Stemer, Uwe Hergenhahn, Tillmann Buttersack, Florian Trinter, Robert Seidel, Wilson Quevedo, Claudia Goy, Iain Wilkinson, Stephan Thürmer, Petr Slavíček, and Bernd Winter;
The Journal of Physical Chemistry A 2021, 125 (32), 6881-6892 DOI: 10.1021/acs.jpca.1c04695
51. Spectroscopic Evidence for a Gold-Coloured Metallic Water Solution
Philip E. Mason, Hanns Christian Schewe, Tillmann Buttersack, Vojtech Kostal, Marco Vitek, Ryan S. McMullen, Hebatallah Ali, Florian Trinter, Chin Lee, Daniel M. Neumark, Stephan Thürmer, Robert Seidel, Bernd Winter, Stephen E. Bradforth, and Pavel Jungwirth;
Nature 2021, 595, 673-676 DOI: 10.1038/s41586-021-03646-5
50. Spin propensity in resonant photoemission of transition metal complexes
Robert H. Temperton, Wilson Quevedo, Robert Seidel, Jens Uhlig, Joachim Schnadt, and Petter Persson;
PHYSICAL REVIEW RESEARCH 2021, 3 (3), 033030 DOI: 10.1103/PhysRevResearch.3.033030
49. Observation of early ZIF-8 crystallization stages with X-ray absorption spectroscopy
Ana Guilherme Buzanich, Anicó Kulow, Anke Kabelitz, Christian Grunewald, Robert Seidel, Ander Chapartegui, Martin Radtke, Uwe Reinholz, Franziska Emmerling, and Sebastian Beyer;
Soft Matter 2021, 17, 331-334 DOI: 10.1039/D0SM01356K
48. Metal–Phenolic Networks as Tunable Buffering Systems
Jingqu Chen, Shuaijun Pan, Jiajing Zhou, Robert Seidel, Sebastian Beyer, Zhixing Lin, Joseph J. Richardson, and Frank Caruso;
Chemistry of Materials 2021, 33 (7), 2557-2566 DOI: 10.1021/acs.chemmater.1c00015
2020
47. Reversible water-induced phase change of cobalt oxide nanoparticles
Dennis Hein, Garlef Wartner, Arno Bergmann, Miguel Bernal, Beatriz Roldan Cuenya, and Robert Seidel;
ACS Nano 2020, 14, 15450-15457 DOI: 10.1021/acsnano.0c06066
46. The electronic structure of the aqueous permanganate ion: aqueous-phase energetics and molecular bonding studied using liquid jet photoelectron spectroscopy
Karen D. Mudryk, Robert Seidel, Bernd Winter, and Iain Wilkinson;
Physical Chemistry Chemical Physics 2020, 22, 20311-20330 DOI: 10.1039/d0cp04033a
45. Nanostructured Boron Doped Diamond Electrodes with Increased Reactivity for Solar‐Driven CO2 Reduction in Room Temperature Ionic Liquids
Peter Knittel, Franziska Buchner, Emina Hadzifejzovic, Christian Giese, Patricia Quellmalz, Robert Seidel, Tristan Petit, Boyan Iliev, Thomas J. S. Schubert, Christoph E. Nebel, and John S. Foord;
ChemCatChem 2020, 12, 1-11 DOI: 10.1002/cctc.202000938
44. Probing the Electronic Structure of Bulk Water at the Molecular Lengthscale with Angle-Resolved Photoelectron Spectroscopy
Robert Seidel, Samer Gozem, Uwe Hergenhahn, Evgeny Lugovoy, Bernd Abel, Bernd Winter, Anna I. Krylov, and Stephen E. Bradforth;
Journal of Physical Chemistry Letters 2020, 11, 5162-5170 DOI: https://dx.doi.org/10.1021/acs.jpclett.0c00968
43. Photoelectron spectra of alkali metal-ammonia microjets: From blue electrolyte to bronze metal
Tillmann Buttersack, Philip E. Mason, Ryan S. McMullen, H. Christian Schewe, Tomas Martinek, Krystof Brezina, Martin Crhan, Axel Gomez, Dennis Hein, Garlef Wartner, Robert Seidel, Hebatallah Ali, Stephan Thürmer, Ondrej Marsalek, Bernd Winter, Stephen E. Bradforth, and Pavel Jungwirth;
Science 2020, 368 (6495), 1086-1091 DOI: 10.1126/science.aaz7607
42. Deeply cooled and temperature controlled microjets: Liquid ammonia solutions released into vacuum for analysis by photoelectron spectroscopy
Tillmann Buttersack, Philip E. Mason, Pavel Jungwirth, H. Christian Schewe, Bernd Winter, Robert Seidel, Ryan S. McMullen, and Stephen E. Bradforth;
Review of Scientific Instruments 2020, 91, 043101 DOI: 10.1063/1.5141359
41. In-Situ X‑ray Spectroscopy of the Electric Double Layer around TiO2 Nanoparticles Dispersed in Aqueous Solution: Implications for H2 Generation
Hebatallah Ali, Ronny Golnak, Robert Seidel, Bernd Winter, and Jie Xiao;
ACS Applied Nano Materials 2020, 3, 264−273 DOI: 10.1021/acsanm.9b01939
2019
40. Improving the Acidic Stability of Zeolitic Imidazolate Frameworks by Biofunctional Molecules
Song Gao, Jingwei Hou, Zeyu Deng, Tiesheng Wang, Sebastian Beyer, Ana Guilherme Buzanich, Joseph J. Richardson, Aditya Rawal, Robert Seidel, Muhammad Yazid Zulkifli, Weiwei Li, Thomas D. Bennett, Anthony K. Cheetham, Kang Liang, and Vicki Chen;
Chem 2019, 5 (6), 1597-1608 DOI: 10.1016/j.chempr.2019.03.025
39. Valence and Core-Level X‑ray Photoelectron Spectroscopy of a Liquid Ammonia Microjet
Tillmann Buttersack, Philip E. Mason, Ryan S. McMullen, Tomas Martinek, Krystof Brezina, Dennis Hein, Hebatallah Ali, Claudia Kolbeck, Christian Schewe, Bernd Winter, Robert Seidel, Ondrej Marsalek, Pavel Jungwirth, and Stephen E. Bradforth
Journal of the American Chemical Society 2019, 141 (5), 1838-1841 DOI: 10.1021/jacs.8b10942
38. Electronic structure of aqueous-phase anatase titanium dioxide nanoparticles probed by liquid jet photoelectron spectroscopy
Hebatallah Ali, Robert Seidel, Arno Bergmann, and Bernd Winter;
Journal of Materials Chemistry A 2019, 7, 6665-6675 DOI: 10.1039/C8TA09414D
37. Do water's electrons care about electrolytes?
Marvin N. Pohl, Eva Muchová, Robert Seidel, Hebatallah Ali, Štěpán Sršeň, Iain Wilkinson, Bernd Winter, and Petr Slavíček;
Chemical Science 2019, 10, 848-865 DOI: 10.1039/c8sc03381a
36. Molecular Arrangement of a Mixture of Organosulfur Surfactants at the Aqueous Solution−Vapor Interface Studied by Photoelectron Intensity and Angular Distribution Measurements and Molecular Dynamics Simulations
Tanza Lewis, Bernd Winter, Stephan Thürmer, Robert Seidel, Anne B. Stephansen, J. Alfredo Freites, Douglas J. Tobias, and John C. Hemminger;
Journal of Physical Chemistry C 2019, 123, 13, 8160-8170 DOI: 10.1021/acs.jpcc.8b08260
2018
35. Molecular species forming at the α-Fe2O3 nanoparticle–aqueous solution interface
Hebatallah Ali, Robert Seidel, Marvin N. Pohl, and Bernd Winter;
Chemical Science 2018, 9 (19), 4511-4523 DOI: 10.1039/c7sc05156e
34. Exploring Redox Properties of Aromatic Amino Acids in Water: Contrasting Single Photon vs Resonant Multiphoton Ionization in Aqueous Solutions
Anirban Roy, Robert Seidel, Gaurav Kumar, and Stephen E. Bradforth;
Journal of Physical Chemistry B 2018, 122 (14), 3723-3733 DOI: 10.1021/acs.jpcb.7b11762
2017
33. Detection of the electronic structure of iron-(III)-oxo oligomers forming in aqueous solutions
Robert Seidel, Katrin Kraffert, Anke Kabelitz, Marvin N. Pohl, Ralph Kraehnert, Franziska Emmerling, and Bernd Winter;
Physical Chemistry Chemical Physics 2017, 19 (7), 32226-32234 DOI: 10.1039/C7CP06945F
32. Advances in liquid phase soft-x-ray photoemission spectroscopy: A new experimental setup at BESSY II
Robert Seidel, Marvin N. Pohl, Hebatallah Ali, Bernd Winter, and Emad F. Aziz;
Review of Scientific Instruments 2017, 88 (7), 073107 DOI: 10.1063/1.4990797
31. Electronic structure of aqueous solutions: Bridging the gap between theory and experiments
Tuan Anh Pham, Marco Govoni, Robert Seidel, Stephen E. Bradforth, Eric Schwegler, and Giulia Galli;
Science Advances 2017, 3 (6), e1603210 DOI: 10.1126/sciadv.1603210
30. Chemical bonding in aqueous hexacyano cobaltate from photon- and electron-detection perspectives
Sreeju Sreekantan Nair Lalithambika, Kaan Atak, Robert Seidel, Antje Neubauer, Tim Brandenburg, Jie Xiao, Bernd Winter, and Emad F. Aziz;
Scientific Reports 2017, 7:40811 DOI: 10.1038/srep40811
29. Sensitivity of Electron Transfer Mediated Decay to Ion Pairing
Marvin N. Pohl, Clemens Richter, Evgeny Lugovoy, Robert Seidel, Petr Slavíček, Emad F. Aziz, Bernd Abel Bernd Winter, and Uwe Hergenhahn;
Journal of Physical Chemistry B 2017, 121 (32), 7709-7714 DOI: 10.1021/acs.jpcb.7b06061
28. Optical Fluorescence Detected from X-ray Irradiated Liquid Water
Andreas Hans, Christian Ozga, Robert Seidel, Philipp Schmidt, Timo Ueltzhöffer, Xaver Holzapfel, Philip Wenzel, Philipp Reiß, Marvin N. Pohl, Isaak Unger, Emad F. Aziz, Arno Ehresmann, Petr Slavíček, Bernd Winter, and André Knie;
Journal of Physical Chemistry B 2017, 121 (10), 2326-2330 DOI: 10.1021/acs.jpcb.7b00096
27. Observation of electron-transfer-mediated decay in aqueous solution
Isaak Unger, Robert Seidel, Stephan Thürmer, Marvin N. Pohl, Emad F. Aziz, Lorenz S. Cederbaum, Eva Muchová, Petr Slavíček, Bernd Winter, and Nikolai V. Kryzhevoi;
Nature Chemistry 2017, 9, 708-714 DOI: 10.1038/NCHEM.2727
26. Aqueous Solution Chemistry of Ammonium Cation in the Auger Time Window
Daniel Hollas, Marvin N. Pohl, Robert Seidel, Emad F. Aziz, Petr Slavíček, and Bernd Winter;
Scientific Reports 2017, 7:756 DOI: 10.1038/s41598-017-00756-x
2016
25. Joint Analysis of Radiative and Non-Radiative Electronic Relaxation Upon X-ray Irradiation of Transition Metal Aqueous Solutions
Ronny Golnak, Sergey Bokarev, Robert Seidel, Jie Xiao, Gilbert Grell, Kaan Atak, Isaak Unger, Stephan Thürmer, Saadullah G. Aziz, Oliver Kühn, Bernd Winter, and Emad F. Aziz;
Scientific Reports 2016, 6:24659 DOI: 10.1038/srep24659
24. Photoelectron Spectra of Aqueous Solutions from First Principles
Alex P. Gaiduk, Marco Govoni, Robert Seidel, Jonathan H. Skone, Bernd Winter, and Giulia Galli;
Journal of the American Chemical Society 2016, 138 (22), 6912-6915283-305 DOI: 10.1021/jacs.6b00225
23. Valence Electronic Structure of Aqueous Solutions: Insights from Photoelectron Spectroscopy
Robert Seidel, Bernd Winter, and Stephen E. Bradforth;
Annual Review of Physical Chemistry 2016, 67, 283-305 DOI: 10.1146/annurev-physchem-040513-103715
22. Undistorted X-ray Absorption Spectroscopy Using s-Core-Orbital Emissions
Ronny Golnak, Jie Xiao, Kaan Atak, Isaak Unger, Robert Seidel, Bernd Winter, and Emad F. Aziz;
Journal of Physical Chemistry A 2016, 120 (18), 2808-2814 DOI: 10.1021/acs.jpca.6b01699
2015
21. Ti3+ Aqueous Solution: Hybridization and Electronic Relaxation Probed by State-Dependent Electron Spectroscopy
Robert Seidel, Kaan Atak, Stephan Thürmer, Emad F. Aziz, and Bernd Winter;
Journal of Physical Chemistry B 2015, 119 (33), 10607-10615 DOI: 10.1021/acs.jpcb.5b03337
20. Control of X-ray Induced Electron and Nuclear Dynamics in Ammonia and Glycine Aqueous Solution via Hydrogen Bonding
Isaak Unger, Daniel Hollas, Robert Seidel, Stephan Thürmer, Emad F. Aziz, Petr Slavíček, and Bernd Winter;
Journal of Physical Chemistry B 2015, 119 (33), 10750-10759 DOI: 10.1021/acs.jpcb.5b07283
19. Multi-reference approach to the calculation of photoelectron spectra including spin-orbit coupling
Gilbert Grell, Sergey I. Bokarev, Robert Seidel, Bernd Winter, Emad F. Aziz, Saadullah G. Aziz, and Oliver Kühn;
Journal of Chemical Physics 2015, 143 (7) DOI: 10.1063/1.4928511
18. Oxidation Half-Reaction of Aqueous Nucleosides and Nucleotides via Photoelectron Spectroscopy Augmented by ab Initio Calculations
Christi A. Schroeder, Eva Pluhařová, Robert Seidel, William P. Schroeder, Manfred Faubel, Petr Slavíček, Bernd Winter, Pavel Jungwirth, and Stephen E. Bradforth;
Journal of the American Chemical Society 2015, 137 (1), 201-209 DOI: 10.1021/ja508149e
17. Exploring the Aqueous Vertical Ionization of Organic Molecules by Molecular Simulation and Liquid Microjet Photoelectron Spectroscopy
Peter R. Tentscher, Robert Seidel, Bernd Winter, Jennifer J. Guerard, and J. Samuel Arey;
Journal of Physical Chemistry B 2015, 119 (1), 238-256 DOI: 10.1021/jp508053m
2014
16. Photoemission Spectra and Density Functional Theory Calculations of 3d Transition Metal-Aqua Complexes (Ti-Cu) in Aqueous Solution
Diana Yepes, Robert Seidel, Bernd Winter, Jochen Blumberger, and Pablo Jaque;
Journal of Physical Chemistry B 2014, 118 (24), 6850-6863 DOI: 10.1021/jp5012389
2013
15. On the nature and origin of dicationic, charge-separated species formed in liquid water on X-ray irradiation
Stephan Thürmer, Milan Ončák, Niklas Ottosson, Robert Seidel, Uwe Hergenhahn, Stephen E. Bradforth, Petr Slavíček, and Bernd Winter;
Nature Chemistry 2013, 5 (7), 590-596 DOI: 10.1038/NCHEM.1680
14. Photoelectron Angular Distributions from Liquid Water: Effects of Electron Scattering
Stephan Thürmer, Robert Seidel, Manfred Faubel, Wolfgang Eberhardt, John C. Hemminger, Stephen E. Bradforth, and Bernd Winter;
Physical Review Letters 2013, 111 (17), 173005 DOI: 10.1103/PhysRevLett.111.173005
13. Unexpectedly Small Effect of the DNA Environment on Vertical Ionization Energies of Aqueous Nucleobases
Eva Pluhařová, Christi Schroeder, Robert Seidel, Stephen E. Bradforth, Bernd Winter, Manfred Faubel, Petr Slavíček, and Pavel Jungwirth;
Journal of Physical Chemistry Letters 2013, 4 (21), 3766-3769 DOI: 10.1021/jz402106h
2012
12. Origin of Dark-Channel X-ray Fluorescence from Transition-Metal Ions in Water
Robert Seidel, Samira Ghadimi, Kathrin M. Lange, Sébastien Bonhommeau, Mikhail A. Soldatov, Ronny Golnak, Alexander Kothe, René Könnecke, Alexander Soldatov, Stephan Thürmer, Bernd Winter, and Emad F. Aziz;
Journal of the American Chemical Society 2012, 134 (3), 1600-1605 DOI: 10.1021/Ja207931r
11. First-Principle Protocol for Calculating Ionization Energies and Redox Potentials of Solvated Molecules and Ions: Theory and Application to Aqueous Phenol and Phenolate
Debashree Ghosh, Anirban Roy, Robert Seidel, Bernd Winter, Stephen Bradforth, and Anna I. Krylov;
Journal of Physical Chemistry B 2012; 116 (24), 7269-7280 DOI: 10.1021/jp301925k
10. Transforming Anion Instability into Stability: Contrasting Photoionization of Three Protonation Forms of the Phosphate Ion upon Moving into Water
Eva Pluhařová, Milan Ončák, Robert Seidel, Christi Schroeder, William Schroeder, Bernd Winter, Stephen E. Bradforth, Pavel Jungwirth, and Petr Slavíček;
Journal of Physical Chemistry B 2012, 116 (44), 13254-13264 DOI: 10.1021/jp306348b
2011
9. Valence Photoemission Spectra of Aqueous Fe(2+/3+) and [Fe(CN)(6)](4-/3-) and Their Interpretation by DFT Calculations
Robert Seidel, Stephan Thürmer, Jan Moens, Paul Geerlings, Jochen Blumberger, and Bernd Winter;
Journal of Physical Chemistry B 2011, 115 (40), 11671-11677 DOI: 10.1021/Jp203997p
8. Flexible H2O2 in Water: Electronic Structure from Photoelectron Spectroscopy and Ab Initio Calculations
Stephan Thürmer, Robert Seidel, Bernd Winter, Milan Ončák, and Petr Slavíček;
Journal of Physical Chemistry A 2011, 115 (23), 6239-6249 DOI: 10.1021/Jp111674s
7. Photoelectron Spectroscopy Meets Aqueous Solution: Studies from a Vacuum Liquid Microjet
Robert Seidel, Stephan Thürmer, and Bernd Winter;
Journal of Physical Chemistry Letters 2011, 2 (6), 633-641DOI: 10.1021/Jz101636y
6. Ultrafast Hybridization Screening in Fe(3+) Aqueous Solution
Stephan Thürmer, Robert Seidel, Wolfgang Eberhardt, Stephen E. Bradforth, and Bernd Winter;
Journal of the American Chemical Society 2011, 133 (32), 12528-12535 DOI: 10.1021/Ja200268b
5. Electronic structure of sub-10 nm colloidal silica nanoparticles measured by in situ photoelectron spectroscopy at the aqueous-solid interface
Matthew A. Brown, Robert Seidel, Stephan Thürmer, Manfred Faubel, John C. Hemminger, Jeroen A. van Bokhoven, Bernd Winter, and Martin Sterrer;
Physical Chemistry Chemical Physics 2011, 13 (28), 12720-12723 DOI: 10.1039/C1cp21131e
2010
4. Energy Levels and Redox Properties of Aqueous Mn2+/3+ from Photoemission Spectroscopy and Density Functional Molecular Dynamics Simulation
Jan Moens, Robert Seidel, Paul Geerlings, Manfred Faubel, Bernd Winter, and Jochen Blumberger;
Journal of Physical Chemistry B 2010, 114 (28), 9173-9182 DOI: 10.1021/Jp101527v
2009
3. Single-Ion Reorganization Free Energy of Aqueous Ru(bpy)(3)(2+/3+) and Ru(H(2)O)(6)(2+/3+) from Photoemission Spectroscopy and Density Functional Molecular Dynamics Simulation
Robert Seidel, Manfred Faubel, Bernd Winter, and Jochen Blumberger;
Journal of the American Chemical Society 2009, 131 (44), 16127-16137 DOI: 10.1021/Ja9047834
2. Spectroscopy of highly charged tungsten ions relevant to fusion plasmas
Christoph Biedermann, Rainer Radtke, Robert Seidel, and Thomas Pütterich;
Physica Scripta 2009, T134, 014026 DOI: DOI: 10.1088/0031-8949/2009/T134/014026
2008
1. Dielectronic and Radiative Recombination of Si- to N-like Tungsten Ions
Christoph Biedermann, Rainer Radtke, Robert Seidel, and Ehud Behar;
14th International Conference on the Physics of Highly Charged Ions (HCI 2008), 163 DOI: 10.1088/1742-6596/163/1/012034