Publications 2022
Ahmet, I.Y.; Abdi, F.F.; van de Krol, R.:
Chemical Treatment of Sn-Containing Transparent Conducting Oxides for the Enhanced Adhesion and Thermal Stability of Electroplated Metals. Advanced Materials Interfaces 9 (2022), p. 2201617/1-15
doi: 10.1002/admi.202201617
Open Access
Akay, O.; Poon, J.; Robertson, C.; Abdi, F.F.; Cuenya, B.R.; Giersig, M.; Brinkert, K.:
Releasing the Bubbles: Nanotopographical Electrocatalyst Design for Efficient Photoelectrochemical Hydrogen Production in Microgravity Environment. Advanced Science 9 (2022), p. 2105380/1-11
doi: 10.1002/advs.202105380
Open Access
Brummel, O.; Lykhach, Y.; Ralaiarisoa, M.; Berasategui, M.; Kastenmeier, M.; Fusek, L.; Simanenko, A.; Gu, W.; Clark, P.C.J.; Yivlialin, R.; Sear, M.J.; Myslivecek, J.; Favaro, M.; Starr, D.E.; Libuda, J.:
A Versatile Approach to Electrochemical In Situ Ambient-Pressure X-ray Photoelectron Spectroscopy: Application to a Complex Model Catalyst. The Journal of Physical Chemistry Letters 13 (2022), p. 11015–11022
doi: 10.1021/acs.jpclett.2c03004
Open Access (external provider)
Clark, P.C.J.; Andresen, E.; Sear, M.J.; Favaro, M.; Girardi, L.; van de Krol, R.; Resch-Genger, U.; Starr, D.E.:
Quantification of the Activator and Sensitizer Ion Distributions in NaYF4:Yb3+, Er3+ Upconverting Nanoparticles Via Depth-Profiling with Tender X-Ray Photoemission. Small 18 (2022), p. 2107976/1-13
doi: 10.1002/smll.202107976
Open Access
De Rosa, S.; Branchini, P.; Spampinato, V.; Franquet, A.; Yivlialin, R.; Duò, L.; Bussetti, G.; Tortora, L.:
Stratigraphic analysis of intercalated graphite electrodes in aqueous inorganic acid solutions. Nano Research 15 (2022), p. 1120-1127
doi: 10.1007/s12274-021-3614-6
Open Access
Ellis, D.S.; Piekner, Y.; Grave, D.A.; Schnell, P.; Rothschild, A.:
Considerations for the Accurate Measurement of Incident Photon to Current Efficiency in Photoelectrochemical Cells. Frontiers in Energy Research 9 (2022), p. 726069/1-14
doi: 10.3389/fenrg.2021.726069
Open Access
Ellis, D.S.; Wang, R.-P.; Wong, D.; Cooper, J.K.; Schulz, C.; Chuang, Y.-D.; Piekner, Y.; Grave, D.A.; Schleuning, M.; Friedrich, D.; de Groot, F.M. F.; Rothschild, A.:
Electronic excitations of α-Fe2O3 heteroepitaxial films measured by resonant inelastic x-ray scattering at the Fe L edge. Physical Review B 105 (2022), p. 075101/1-10
doi: 10.1103/PhysRevB.105.075101
Open Access (external provider)
El-Nagar, G.A.; Yang, F.; Stojkovikj, S.; Mebs, S.; Gupta, S.; Ahmet, I.Y.; Dau, H.; Mayer, M.T.:
Comparative Spectroscopic Study Revealing Why the CO2 Electroreduction Selectivity Switches from CO to HCOO– at Cu–Sn- and Cu–In-Based Catalysts. ACS Catalysis 12 (2022), p. 15576–15589
doi: 10.1021/acscatal.2c04419
Open Access
Fareza, A.R.; Nugroho, F.A.A.; Abdi, F.F.; Fauzia, V.:
Nanoscale metal oxides-2D materials heterostructures for photoelectrochemical water splitting-a review. Journal of Materials Chemistry A 10 (2022), p. 8656-8686
doi: 10.1039/d1ta10203f
Open Access
Flatken, M.A.; Radicchi, E.; Wendt, R.; Guilherme Buzanich, A.; Härk, E.; Pascual, J.; Mathies, F.; Shargaieva, O.; Prause, A.; Dallmann, A.; De Angelis, F.; Hoell, A.; Abate, A.:
Role of the Alkali Metal Cation in the Early Stages of Crystallization of Halide Perovskites. Chemistry of Materials 34 (2022), p. 1121–1131
doi: 10.1021/acs.chemmater.1c03563
Gahlawat, S.; Ahmet, I.Y.; Schnell, P.; Levine, I.; Zhang, S.; Ingole, P.P.; Abdi, Fatwa F.:
Enhancing the Photon Absorption and Charge Carrier Dynamics of BaSnO3 Photoanodes via Intrinsic and Extrinsic Defects. Chemistry of Materials 34 (2022), p. 4320–4335
doi: 10.1021/acs.chemmater.1c04129
Gahlawat, S.; Schnell, P.; Irani, R.; Ahmet, I.Y.; Choubrac, L.; Fiechter, S.; Ingole, P.P.; Abdi, F.F.:
Extending the Absorption Limit of BiVO4 Photoanodes with Hydrogen Sulfide Treatment. Solar RRL 6 (2022), p. 2200129/1-7
doi: 10.1002/solr.202200129
Open Access
Gottesman, R.; Peracchi, I.; Gerke, J.L.; Irani, R.; Abdi, F.F.; Van De Krol, R.:
Shining a Hot Light on Emerging Photoabsorber Materials: The Power of Rapid Radiative Heating in Developing Oxide Thin-Film Photoelectrodes. ACS Energy Letters 7 (2022), p. 514-522
doi: 10.1021/acsenergylett.1c02220
Open Access
Heilmann, M.; Prinz, C.; Bienert, R.; Wendt, R.; Kunkel, B.; Radnik, J.; Hoell, A.; Wohlrab, S.; Guilherme Buzanich, A.; Emmerling, F.:
Size-Tunable Ni-Cu Core-Shell Nanoparticles - Structure, Composition, and Catalytic Activity for the Reverse Water-Gas Shift Reaction. Advanced Engineering Materials 24 (2022), p. 2101308/1-13
doi: 10.1002/adem.202101308
Open Access
Hempel, H.; Savenjie, T.J.; Stolterfoht, M.; Neu, J.; Failla, M.; Paingad, V.C.; Kuzel, P.; Heilweil, E.J.; Spies, J.A.; Schleuning, M.; Zhao, J.; Friedrich, D.; Schwarzburg, K.; Siebbeles, L.D.A.; Dörflinger, P.; Dyakonov, V.; Katoh, R.; Hong, M.J.; Labram, J.G.; Monti, M.; Butler-Caddle, E.; Lloyd-Hughes, J.; Taheri, M.M.; Baxter, J.B.; Magnanelli, T.J.; Luo, S.; Cardon, J.M.; Ardo, S.; Unold, T.:
Predicting Solar Cell Performance from Terahertz and Microwave Spectroscopy. Advanced Energy Materials 12 (2022), p. 2102776/1-16
doi: 10.1002/aenm.202102776
Open Access
Jian, J.; Wang, S.; Ye, Q.; Li, F.; Su, G.; Liu, W.; Qu, C.; Liu, F.; Li, C.; Jia, L.; Novikov, A.A.; Vinokurov, V.A.; Harvey, D.H.S.; Shchukin, D.; Friedrich, D.; van de Krol, R.; Wang, H.:
Activating a Semiconductor-Liquid Junction via Laser-Derived Dual Interfacial Layers for Boosted Photoelectrochemical Water Splitting. Advanced Materials 34 (2022), p. 2201140/1-12
doi: 10.1002/adma.202201140
Kern, L.M.; Pfau, B.; Deinhart, V.; Schneider, M.; Klose, C.; Gerlinger, K.; Wittrock, S.; Engel, D.; Will, I.; Günther, C.M.; Liefferink, R.; Mentink, J.H.; Wintz, S.; Weigand, M.; Huang, M.J.; Battistelli, R.; Metternich, D.; Büttner, F.; Höflich, K.; Eisebitt, S.:
Deterministic Generation and Guided Motion of Magnetic Skyrmions by Focused He+-Ion Irradiation. Nano Letters 22 (2022), p. 4028-4035
doi: 10.1021/acs.nanolett.2c00670
Open Access (external provider)
Kölbach, M.; Höhn, O.; Rehfeld, K.; Finkbeiner, M.; Barry, J.; May, M. M.:
The annual-hydrogen-yield-climatic-response ratio: evaluating the real-life performance of integrated solar water splitting devices. Sustainable Energy & Fuels 6 (2022), p. 4062-4074
doi: 10.1039/d2se00561a
Özen, C.; Obata, K.; Bogdanoff, P.; Yulianto, N.; Wasisto, H.S.; Abdi, F.F.:
Transparent porous polymer sheets for efficient product separation in solar water splitting. Sustainable Energy & Fuels 6 (2022), p. 377-385
doi: 10.1039/d1se01475g
Open Access
Pardo Pérez, L.C.; Arndt, A.; Stojkovikj, S.; Ahmet, I.Y.; Arens, J.T.; Dattila, F.; Wendt, R.; Guilherme Buzanich, A.; Radtke, M.; Davies, V.; Höflich, K.; Köhnen, E.; Tockhorn, P.; Golnak, R.; Xiao, J.; Schuck, G.; Wollgarten, M.; López, N.; Mayer, M.T.:
Determining Structure-Activity Relationships in Oxide Derived Cu-Sn Catalysts During CO2 Electroreduction Using X-Ray Spectroscopy. Advanced Energy Materials 12 (2022), p. 2103328/1-16
doi: 10.1002/aenm.202103328
Open Access
Pardo Pérez, L.C.; Chalkley, Z.; Wendt, R.; Ahmet, I.Y.; Wollgarten, M.; Mayer, M.T.:
CO2 electroreduction activity and dynamic structural evolution of in situ reduced nickel-indium mixed oxides. Journal of Materials Chemistry A 10 (2022), p. 20593-20605
doi: 10.1039/d2ta05214h
Open Access
Piekner, Y.; Ellis, D.S.; Schleuning, M.; Grave, D.A.; Schnell, P.; Dotan, H.; Abdi, F.F.; Rothschild, A.:
External Quantum Efficiency Spectra of BiVO4 Thin Film Photoanodes under Bias Illumination. Journal of The Electrochemical Society 169 (2022), p. 046513/1-8
doi: 10.1149/1945-7111/ac63f7
Prabhakar, R.R.; Moehl, T.; Friedrich, D.; Kunst, M.; Shukla, S.; Adeleye, D.; Damle, V.H.; Siol, S.; Cui, W.; Gouda, L.; Suh, J.; Tischler, Y.R.; van de Krol, R.; Tilley, S.D.:
Sulfur-Treatment Passivates Bulk Defects in Sb2Se3 Photocathodes for Water Splitting. Advanced Functional Materials 23 (2022), p. 2112184/1-7
doi: 10.1002/adfm.202112184
Open Access
Rodriguez, J.A.; Tait, S.L.; Starr, D.E.:
Preface. Surface Science 717 (2022), p. 1-2
doi: 10.1016/j.susc.2021.122003
Schleuning, M.; Ahmet, I.Y.; van de Krol, R.; May, M.M.:
The role of selective contacts and built-in field for charge separation and transport in photoelectrochemical devices. Sustainable Energy & Fuels 6 (2022), p. 3701-3716
doi: 10.1039/d2se00562j
Open Access
Schleuning, M.; Kölbach, M.; Abdi, F.F.; Schwarzburg, K.; Stolterfoht, M.; Eichberger, R.; Van de Krol, R.; Friedrich, D.; Hempel, H.:
Generalized Method to Extract Carrier Diffusion Length from Photoconductivity Transients: Cases of BiVO4, Halide Perovskites, and Amorphous and Crystalline Silicon. PRX Energy 1 (2022), p. 023008/1-13
doi: 10.1103/PRXEnergy.1.023008
Open Access
Schnell, P.; Dela Cruz, J. M.C. M.; Koelbach, M.; van de Krol, R.; Abdi, F.F.:
pH-Dependent Stability of α-SnWO4 Photoelectrodes. Chemistry of Materials 34 (2022), p. 1590–1598
doi: 10.1021/acs.chemmater.1c03517
Segev, G.; Kibsgaard, J.; Hahn, C.; Xu, Z.J.; Cheng, W.-H.; Deutsch, T.G.; Xiang, C.; Zhang, J.Z.; Hammarstrom, L.; Nocera, D.G.; Weber, A.Z.; Agbo, P.; Hisatomi, T.; Osterloh, F.E.; Domen, K.; Abdi, F.F.; Haussener, S.; Miller, D.J.; Ardo, S.; McIntyre, P.C.; Hannappel, T.; Hu, S.; Atwater, H.; Gregoire, J.M.; Ertem, M.Z.; Sharp, I.D.; Choi, K.-S.; Lee, J.S.; Ishitani, O.; Ager, J.W.; Prabhakar, R.R.; Bell, A.T.; Boettcher, S.W.; Vincent, K.; Takanabe, K.; Artero, V.; Napier, R.; Cuenya, B.R.; Koper, M.T. M.; Van de Krol, R.; Houle, F.:
The 2022 solar fuels roadmap. Journal of Physics D 55 (2022), p. 323003/1-52
doi: 10.1088/1361-6463/ac6f97
Open Access
Starr, D.E.; Hävecker, M.; Knop-Gericke, A.; Favaro, M.; Vadilonga, S.; Mertin, M.; Reichardt, G.; Schmidt, J.S.; Siewert, F.; Schulz, R.; Viefhaus, J.; Jung, C.; van de Krol, R.:
The Berlin Joint Lab for Electrochemical Interfaces, BElChem: A Facility for In-situ and Operando NAP-XPS and NAP-HAXPES Studies of Electrochemical Interfaces at BESSY II. Synchrotron Radiation News 35 (2022), p. 54-60
doi: 10.1080/08940886.2022.2082209
Open Access
Thamm, A.K.; Wei, J.; Zhou, J.; Walker, C.G.H.; Cabrera, H.; Demydenko, M.; Pescia, D.; Ramsperger, U.; Suri, A.; Pratt, A.; Tear, S.P.; El-Gomati, M.M.:
Hallmark of quantum skipping in energy filtered lensless scanning electron microscopy. Applied Physics Letters 120 (2022), p. 052403/1-6
doi: 10.1063/5.0077503
Open Access
Thiel, T. A.; Zhang, X.; Radhakrishnan, B.; van de Krol, R.; Abdi, F.F.; Schroeter, M.; Schomaecker, R.; Schwarze, M.:
Kinetic investigation of para-nitrophenol reduction with photodeposited platinum nanoparticles onto tunicate cellulose. RSC Advances 12 (2022), p. 30860-30870
doi: 10.1039/d2ra05507d
Open Access
Thiel, T.A.; Obata, K.; Abdi, F.F.; van de Krol, R.; Schomäcker, R.; Schwarze, M.:
Photocatalytic hydrogenation of acetophenone on a titanium dioxide cellulose film. RSC Advances 12 (2022), p. 7055-7065
doi: 10.1039/d1ra09294d
Open Access
Toe, C.Y.; Lamers, M.; Dittrich, T.; Tahini, H.A.; Smith, S.C.; Scott, J.; Amal, R.; van de Krol, R.; Abdi, F.F.; Ng, Y.H.:
Facet-dependent carrier dynamics of cuprous oxide regulating the photocatalytic hydrogen generation. Materials Advances 3 (2022), p. 2200-2212
doi: 10.1039/d1ma00934f
Open Access
Utke, I.; Swiderek, P.; Höflich, K.; Madajska, K.; Jurczyk, J.; Martinovic, P.; Szymanska, I.B.:
Coordination and organometallic precursors of group 10 and 11: Focused electron beam induced deposition of metals and insight gained from chemical vapour deposition, atomic layer deposition, and fundamental surface and gas phase studies. Coordination Chemistry Reviews 458 (2022), p. 213851/1-64
doi: 10.1016/j.ccr.2021.213851
Open Access
Wang, W.; Favaro, M.; Chen, E.; Trotochaud, L.; Bluhm, H.; Choi, K.-S.; van de Krol, R.; Starr, D.E.; Galli, G.:
Influence of Excess Charge on Water Adsorption on the BiVO4(010) Surface. Journal of the American Chemical Society 144 (2022), p. 17173–17185
doi: 10.1021/jacs.2c07501
Open Access
Wu, H.; Zhang, L.; Du, A.; Irani, R.; van de Krol, R.; Abdi, F.F.; Ng, Y.H.:
Low-bias photoelectrochemical water splitting via mediating trap states and small polaron hopping. Nature Communications 13 (2022), p. 6231/1-12
doi: 10.1038/s41467-022-33905-6
Open Access
Xi, F.; Bozheyev, F.; Han, X.; Rusu, M.; Rappich, J.; Abdi, F.; Bogdanoff, P.; Kaltsoyannis, N.; Fiechter, S.:
Enhancing Hydrogen Evolution Reaction via Synergistic Interaction between the [Mo3S13]2– Cluster Co-Catalyst and WSe2 Photocathode. ACS Applied Materials & Interfaces 14 (2022), p. 52815–52824
doi: 10.1021/acsami.2c14312
Open Access
Yang, J.; Ghosh, S.; Roeser, J.; Acharjya, A.; Penschke, C.; Tsutsui, Y.; Rabeah, J.; Wang, T.; Djoko Tameu, S.Y.; Ye, M.Y.; Grüneberg, J.; Li, S.; Li, C.; Schomäcker, R.; Van De Krol, R.; Seki, S.; Saalfrank, P.; Thomas, A.:
Constitutional isomerism of the linkages in donor-acceptor covalent organic frameworks and its impact on photocatalysis. Nature Communications 13 (2022), p. 6317/1-10
doi: 10.1038/s41467-022-33875-9
Open Access
Zhang, M.; Fang, Y.; Tay, Y.F.; Liu, Y.; Wang, L.; Jani, H.; Abdi, F.F.; Wong, L.H.:
Nanostructured Iron Vanadate Photoanodes with Enhanced Visible Absorption and Charge Separation. ACS Applied Energy Materials 5 (2022), p. 3409
doi: 10.1021/acsaem.1c04004