Business card Dr. Dirk Wallacher
- graduate physicist
- Department Sample Environments
Experimental scientist and expert for research on nanostructured and interface determined materials and characterization by gas adsorption analysis combined with neutron and x-ray scattering techniques. Scientific focus are on fundamental research in the thermodynamics and structure of meso-scaled pore condensates as well as the sorption properties of gas storage materials and molecular sieves. Responsible at Helmholtz-Centre Berlin for scientific and technical user support at the neutron source BER-II and the synchrotron light source BESSY-II for sample environment concerning: high pressures and temperatures, controlled gas atmospheres, cryogen free cryostats, operando experiments as well as for the operation of the complementary HZB user lab DEGAS for gas adsorption studies.
List of publications at HZB
2024
Thum, L.; Arztmann, M.; Zizak, I.; Grüneberger, R.; Steigert, A.; Grimm, N.; Wallacher, D.; Schlatmann, R.; Amkreutz, D.; Gili, A.: In situ cell for grazing-incidence x-ray diffraction on thin films in thermal catalysis. Review of Scientific Instruments 95 (2024), p. 033904/1-7
2023
Hunvik, K.W.B.; Seljelid, K.K.; Wallacher, D.; Kirch, A.; Cavalcanti, L.P.; Loch, P.; Røren, P.M.; Michels-Brito, P.H.; Droppa Jr., R.; Knudsen, K.D.; Miranda, C.R.; Breu, J.; Fossum, J.O.: Intercalation of CO2 Selected by Type of Interlayer Cation in Dried Synthetic Hectorite. Langmuir 39 (2023), p. 4895-4903
Trinh, C.; Wei, Y.; Yadav, A.; Muske, M.; Grimm, N.; Li, Z.; Thum, L.; Wallacher, D.; Schlögl, R.; Skorupska, K.; Schlatmann, R.; Amkreutz, D.: Reactor design for thin film catalyst activity characterization. Chemical Engineering Journal 477 (2023), p. 146926/1-10
2022
Krause, S.; Evans, J.D.; Bon, V.; Crespi, S.; Danowski, W.; Browne, W.R.; Ehrling, S.; Walenszus, F.; Wallacher, D.; Grimm, N.; Többens, D.M.; Weiss, M.S.; Kaskel, S.; Feringa, B.L.: Cooperative light-induced breathing of soft porous crystals via azobenzene buckling. Nature Communications 13 (2022), p. 1951/1-10
Schuck, G.; Többens, D.M.; Wallacher, D.; Grimm, N.; Tien, T.S.; Schorr, S.: Temperature-Dependent EXAFS Measurements of the Pb L3-Edge Allow Quantification of the Anharmonicity of the Lead–Halide Bond of Chlorine-Substituted Methylammonium (MA) Lead Triiodide. The Journal of Physical Chemistry C 126 (2022), p. 5388–5402
2021
Barthel, T.; Huschmann, F.U.; Wallacher, D.; Feiler, C.G.; Klebe, G.; Weiss, M.S.; Wollenhaupt, J.: Facilitated crystal handling using a simple device for evaporation reduction in microtiter plates. Journal of Applied Crystallography 54 (2021), p. 376-382
Bø Hunvik, K.W.; Loch, P.; Wallacher, D.; Kirch, A.; Cavalcanti, L.P.; Rieß, M.; Daab, M.; Josvanger, V.; Grätz, S.; Yokaichiya, F.; Knudsen, K.D.; Rodrigues Miranda, C.; Breu, J.; Fossum, J.O.: CO2 Adsorption Enhanced by Tuning the Layer Charge in a Clay Mineral. Langmuir 37 (2021), p. 14491/1-9
Bon, V.; Krause, S.; Senkovska, I.; Grimm, N.; Wallacher, D.; Többens, D.M.; Kaskel, S.: Massive Pressure Amplification by Stimulated Contraction of Mesoporous Frameworks. Angewandte Chemie - International Edition 60 (2021), p. 11735-11739
Casco, M.E.; Grätz, S.; Wallacher, D.; Grimm, N.; Többens, D.M.; Bilo, M.; Speil, N.; Fröba, M.; Borchardt, L.: Influence of surface wettability on methane hydrate formation in hydrophilic and hydrophobic mesoporous silicas. Chemical Engineering Journal 405 (2021), p. 126955/1-11
Finger, R.; Widenmeyer, M.; Hansen, T.C.; Wallacher, D.; Savvin, S.; Bertmer, M.; Weidenkaff, A.; Kohlmann, H.: Effects of Cr Doping and Water Content on the Crystal Structure Transitions of Ba2In2O5. Crystals (Basel) 11 (2021), p. 1548/1-19
Gericke, E.; Wallacher, D.; Wendt, R.; Greco, G.; Krumrey, M.; Raoux, S.; Hoell, A.; Mascotto, S.: Direct Observation of the Xenon Physisorption Process in Mesopores by Combining In Situ Anomalous Small-Angle X-ray Scattering and X-ray Absorption Spectroscopy. The Journal of Physical Chemistry Letters 12 (2021), p. 4018-4023
Hofmann, T.; Kojda, D.; Haseeb, H.; Wallacher, D.; Sobolev, O.; Habicht, K.: Phonons in highly-crystalline mesoporous silicon: The absence of phonon-softening upon structuring silicon on sub-10 nanometer length scales. Microporous and Mesoporous Materials 312 (2021), p. 110814/1-7
Krause, S.; Evans, J.D.; Bon, V.; Senkovska, I.; Coudert, F.X.; Többens, D.M.; Wallacher, D; Grimm, N; Kaskel, S.: The role of temperature and adsorbate on negative gas adsorption transitions of the mesoporous metal-organic framework DUT-49. Faraday Discussions 225 (2021), p. 168-183
Wollenhaupt, J.; Barthel, T.; Lima, G.M.A.; Metz, A.; Wallacher, D.; Jagudin, E.; Huschmann, F.U.; Hauß, T.; Feiler, C.G.; Gerlach, M.; Hellmig, M.; Förster, R.; Steffien, M.; Heine, A.; Klebe, G.; Mueller, U.; Weiss, M.S.: Workflow and Tools for Crystallographic Fragment Screening at the Helmholtz-Zentrum Berlin. Journal of visualized experiments : JoVE 169 (2021), p. e6220/1-19 + video
2020
Badaczewski, F.M.; Loeh, M.O.; Pfaff, T.; Wallacher, D.; Clemens, D.; Smarsly, B.M.: An advanced structural characterization of templated meso-macroporous carbon monoliths by small- and wide-angle scattering techniques. Beilstein Journal of Nanotechnology 11 (2020), p. 310-322
Badaczewski, F.M.; Loeh, M.O.; Pfaff, T.; Wallacher, D.; Clemens, D.; Smarsly, B.M.: Correction: An advanced structural characterization of templated meso-macroporous carbon monoliths by small- and wide-angle scattering techniques. Beilstein Journal of Nanotechnology 11 (2020), p. 678-679
Gostkowska-Lekner, N.; Wallacher, D.; Grimm, N.; Habicht, K.; Hofmann, T.: A novel electrochemical anodization cell for the synthesis of mesoporous silicon. Review of Scientific Instruments 91 (2020), p. 105113/1-6
Hunvik, K.W.B.; Loch, P.; Cavalcanti, L.P.; Seljelid, K.K.; Røren, P.M.; Rudic, S.; Wallacher, D.; Kirch, A.; Knudsen, K.D.; Rodrigues Miranda, C.; Breu, J.; Bordallo, H.N.; Fossum, J.O.: CO2 Capture by Nickel Hydroxide Interstratified in the Nanolayered Space of a Synthetic Clay Mineral. The Journal of Physical Chemistry C 124 (2020), p. 26222–26231
Kim, J. Y.; Park, J.; Ha, J.; Jung, M.; Wallacher, D.; Franz, A.; Balderas-Xicohténcatl, R.; Hirscher, M.; Kang, S. G.; Park, J.; Oh, I.H.; Moon, H. R.; Oh, H.: Specific Isotope-Responsive Breathing Transition in Flexible Metal-Organic Frameworks. Journal of the American Chemical Society 142 (2020), p. 13278-13282
Krause, S.; Evans, J.D.; Bon, V.; Senkovska, I.; Ehrling, S.; Iacomi, P.; Többens, D.M.; Wallacher, D.; Weiss, M.S.; Zheng, B.; Yot, P.G.; Maurin, G.; Llewellyn, P.L.; Coudert, F.X.; Kaskel, S.: Engineering micromechanics of soft porous crystals for negative gas adsorption. Chemical Science 11 (2020), p. 9468-9479
Kube, S.A.; Turke, K.; Ellinghaus, R.; Wallacher, D.; Thommes, M.; Smarsly, B.: Pore size gradient effect in monolithic silica mesopore networks revealed by in-situ-SAXS-physisorption. Langmuir 36 (2020), p. 11996-12009
Zhánal, P.; Ryukhtin, V.; Farkas, G.; Kadletz, P.; Keiderling, U.; Wallacher, D.; Harcuba, P.: Evolution of distance between ω particles in metastable β-Ti alloy determined from in-situ small angle neutron scattering. In: The 14th World Conference on Titanium (Ti 2019) : Nantes, France, June 10-14 2019Les Ulis: edp sciences, 2020 (MATEC Web of Conferences ; 321), p. 12027/1-7
2019
Badaczewski, F.; Loeh, M.O.; Pfaff, T.; Dobrotka, S.; Wallacher, D.; Clemens, D.; Metz, J.; Smarsly, B.: Peering into the structural evolution of glass-like carbons derived from phenolic resin by combining small-angle neutron scattering with an advanced evaluation method for wide-angle X-ray scattering. Carbon 141 (2019), p. 169-181
Casco, M.E.; Zhang, En; Grätz, S.; Krause, S.; Bon, V.; Wallacher, D.; Grimm, N.; Többens, D.M.; Hauß, T.; Borchardt, L.: Experimental Evidence of Confined Methane Hydrate in Hydrophilic and Hydrophobic Model Carbons. The Journal of Physical Chemistry C 123 (2019), p. 24071-24079
Czub, J.; Jamka, W.; Przewoznik, J.; Zarzecka, A.; Hoser, A.; Wallacher, D.; Grimm, N.; Gondek, Gondek: Structural peculiarities in the beta phase of the La0.75Ce0.25Ni4.8Al0.2 deuterides. Journal of Alloys and Compounds 788 (2019), p. 533-540
Feiler, C.G.; Wallacher, D.; Weiss, M.S.: An All-in-one Sample Holder for Macromolecular X-ray Crystallography with Minimal Background Scattering. Journal of visualized experiments : JoVE 149 (2019), p. e59722/1-10 + video
Gonthier, J.; Barrett, M.; Aguettaz, O.; Baudoin, S.; Bourgeat-Lami, E.; Demé, B.; Grimm, N.; Hauß, T.; Kiefer, K.; Lelièvre-Berna, E.; Perkins, A.; Wallacher, D.: BerILL: The ultimate humidity chamber for neutron scattering. Journal of Neutron Research 21 (2019), p. 65-76
Krause, S.; Evans, J.D.; Bon, V.; Senkovska, I.; Iacomi, P.; Kolbe, F.; Ehrling, S.; Troschke, E.; Getzschmann, J.; Többens, D.; Franz, A.; Wallacher, D.; Yot, P.G.; Maurin, G.; Brunner, E.; Llewellyn, P.L.; Coudert, F.-X.; Kaskel, S.: Towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworks. Nature Communications 10 (2019), p. 3632/1-12
Ranieri, U.; Koza, M.M.; Kuhs, W.F.; Gaal, R.; Klotz, S.; Falenty, A.; Wallacher, D.; Ollivier, J.; Gillet, P.; Bove, L.E.: Quantum Dynamics of H2 and D2 Confined in Hydrate Structures as a Function of Pressure and Temperature. The Journal of Physical Chemistry C 123 (2019), p. 1888-1903
Zhang, L.; Jee, S.; Park, J.; Jung, M.; Wallacher, D.; Franz, A.; Lee, W.; Yoon, M.; Choi, K.; Hirscher, M.; Oh, H.: Exploiting Dynamic Opening of Apertures in a Partially Fluorinated MOF for Enhancing H2 Desorption Temperature and Isotope Separation. Journal of the American Chemical Society 141 (2019), p. 19850-19858
2018
Krause, S.; Bon, V.; Senkovska, I.; Többens, D.; Wallacher, D.; Pillai, R.; Maurin, G.; Kaskel, S.: The effect of crystallite size on pressure amplification in switchable porous solids. Nature Communications 9 (2018), p. 1573
Russina, M.; Guenther, G.; Grzimek, V.; Gainov, R.; Schlegel, M.; Drescher, L.; Kaulich, T.; Graf, W.; Urban, B.; Daske, A.; Grotjahn, K.; Hellhammer, R.; Buchert, G.; Kutz, H.; Rossa, L.; Sauer, O.-P.; Fromme, M.; Wallacher, D.; Kiefer, K.; Klemke, B.; Grimm, N.; Gerischer, S.; Tsapatsaris, N.; Rolfs, K.: Upgrade project NEAT'2016 at Helmholtz Zentrum Berlin - What can be done on the medium power neutron source. Physica B 551 (2018), p. 506-511
2017
Auer, H.; Wallacher, D.; Hansen, T.C.; Kohlmann, H.: In Situ Hydrogenation of the Zintl Phase SrGe. Inorganic Chemistry 56 (2017), p. 1072-1079
Busch, M.; Kityk, A.V.; Piecek, W.; Hofmann, T.; Wallacher, D.; Calus, S.; Kula, P.; Steinhart, M.; Eich, M.; Huber, P.: A ferroelectric liquid crystal confined in cylindrical nanopores: reversible smectic layer buckling, enhanced light rotation and extremely fast electro-optically active Goldstone excitations. Nanoscale 9 (2017), p. 19086-19099
Hofmann, T.; Wallacher, D.; Toft-Petersen, R.; Ryll, B.; Reehuis, M.; Habicht, K.: Phonons in mesoporous silicon: The influence of nanostructuring on the dispersion in the Debye regime. Microporous and Mesoporous Materials 243 (2017), p. 263-270
Jafta, C.J.; Petzold, A.; Risse, S.; Clemens, D.; Wallacher, D.; Goerigk, G.; Ballauff, M.: Correlating pore size and shape to local disorder in microporous carbon: A combined small angle neutron and X-ray scattering study. Carbon 123 (2017), p. 440-447
Klimkowicz, A.; Swierczek, K.; Zheng, K.; Wallacher, D.; Takasaki, A.: Oxygen release from BaLnMn2O6 (Ln: Pr, Nd, Y) under reducing conditions as studied by neutron diffraction. Journal of Materials Science 52 (2017), p. 6476-6485
Krause, S.; Bon, V.; Stoeck, U.; Senkovska, I.; Többens, D.; Wallacher, D.; Kaskel, S.: A Stimuli-Responsive Zirconium Metal-Organic Framework Based on Supermolecular Design. Angewandte Chemie - International Edition 56 (2017), p. 10676-10680
Krause, S.; Bon, V.; Stoeck, U.; Senkovska, I.; Többens, D.; Wallacher, D.; Kaskel, S.: A Stimuli-Responsive Zirconium Metal–Organic Framework Based on Supermolecular Design. Angewandte Chemie 129 (2017), p. 10816-10820
Schaber, J.; Krause, S.; Paasch, S.; Senkovska, I.; Bon, V.; Többens, D.; Wallacher, D.; Kaskel, S.; Brunner, E.: In Situ Monitoring of Unique Switching Transitions in the Pressure-Amplifying Flexible Framework Material DUT-49 by High-Pressure 129Xe NMR Spectroscopy. The Journal of Physical Chemistry C 121 (2017), p. 5195-5200
2016
Bon, V.; Kavoosi, N.; Senkovska, I.; Müller, P.; Schaber, J.; Wallacher, D.; Többens, D.M.; Mueller, U.; Kaskel, S.: Tuning the flexibility in MOFs by SBU functionalization. Dalton Transactions 45 (2016), p. 4407-4415
Borchardt, L.; Nickel, W.; Casco, M.; Senkovska, I.; Bon, V.; Wallacher, D.; Grimm, N.; Krause, S.; Silvestre-Albero, J.: Illuminating solid gas storage in confined spaces – methane hydrate formation in porous model carbons. Physical Chemistry Chemical Physics 18 (2016), p. 20607/1-8
Cairns, A.J.; Eckert, J.; Wojtas, L.; Thommes, M.; Wallacher, D.; Georgiev, P.A.; Forster, P.M.; Belmabkhout, Y.; Ollivier, J.; Eddaoudi, M.: Gaining Insights on the H2–Sorbent Interactions: Robust soc-MOF Platform as a Case Study. Chemistry of Materials 28 (2016), p. 7353-7361
Gruener, S.; Wallacher, D.; Greulich, S.; Busch, M.; Huber, P.: Hydraulic transport across hydrophilic and hydrophobic nanopores: Flow experiments with water and n-hexane. Physical Review E 93 (2016), p. 013102/1-13
Hofmann, T.; Wallacher, D.; Perlich, J.; Vayalil, S.K.; Huber, P.: Formation of Periodically Arranged Nanobubbles in Mesopores: Capillary Bridge Formation and Cavitation during Sorption and Solidification in an Hierarchical Porous SBA-15 Matrix. Langmuir 32 (2016), p. 2928-2936
Krause, S.; Bon, V.; Senkovska, I.; Stoeck, U.; Wallacher, D.; Többens, D.; Zander, S.; Pillai, R.S.; Maurin, G.; Coudert, F.X.; Kaskel, S.: A pressure-amplifying framework with negative gas adsorption transitions. Nature 532 (2016), p. 348-352
Schlegel, M.-C.; Többens, D.M.; Svetogorov, R.; Krüger, M.; Stock, N.; Reinsch, H.; Wallacher, D.; Stewart, R.; Russina, M.: Conformation-controlled hydrogen storage in the CAU-1 metal-organic framework. Physical Chemistry Chemical Physics 18 (2016), p. 29258-29267
2015
Bon, V.; Klein, N.; Senkovska, I.; Heerwig, A.; Getzschmann, J.; Wallacher, D.; Zizak, I.; Brzhezinskaya, M.; Müller, U.; Kaskel, S.: Exceptional adsorption-induced cluster and network deformation in the flexible metal–organic framework DUT-8(Ni) observed by in situ X-ray diffraction and EXAFS. Physical Chemistry Chemical Physics 17 (2015), p. 17471-17479
Bon, V.; Pallmann, J.; Eisbein, E.; Hoffmann, H.C.; Senkovska, I.; Schwedler, I.; Schneemann, A.; Henke, S.; Wallacher, D.; Fischer, R.A.; Seifert, G.; Brunner, E.; Kaskel, S.: Characteristics of flexibility in metal-organic framework solid solutions of composition [Zn2(BME-bdc)x(DB-bdc)2-xdabco]n: In situ powder X-ray diffraction. Microporous and Mesoporous Materials 216 (2015), p. 64–74
Kunkel, N.; Reichert, C.; Springborg, M.; Wallacher, D.; Kohlmann, H.: Hydrogenation properties of LixSr1-xAlSi studied by quantum-chemical methods (0≤x≤1) and in-situ neutron powder diffraction (x=1). Journal of Solid State Chemistry 211 (2015), p. 318-324
Mascotto, S.; Kuzmicz, D.; Wallacher, D.; Siebenbürger, M.; Clemens, D.; Risse, S.; Yuan, J.; Antonietti, M.; Ballauff, M.: Poly(ionic liquid)-derived nanoporous carbon analyzed by combination of gas physisorption and small-angle neutron scattering. Carbon 82 (2015), p. 425-435
Stoeckel, D.; Wallacher, D.; Zickler, G.; Thommes, M.; Smarsly, B.: Elucidating the Sorption Mechanism of Dibromomethane in Disordered Mesoporous Silica Adsorbents. Langmuir 31 (2015), p. 6332-6342
Weidemann, S.; Kockert, M.; Wallacher, D.; Ramsteiner, M.; Mogilatenko, A.; Rademann, K.; Fischer, S.F.: Controlled Pore Formation on Mesoporous Single Crystalline Silicon Nanowires: Threshold and Mechanisms. Journal of Nanomaterials 2015 (2015), p. 672305/1-11
2014
Bon, V.; Sekovska, I.; Wallacher, D.; Többens, D.; Zizak, I.; Feyerherm, R.; Mueller, U.; Kaskel, S.: In Situ Observation of Gating Phenomena in the Flexible Porous Coordination Polymer Zn2(BPnDC)2(bpy) (SNU-9) in a Combined Diffraction and Gas Adsorption Experiment. Inorganic Chemistry 53 (2014), p. 1513-1520
Bon, V.; Senkovska, I.; Wallacher, D.; Heerwig, A.; Klein, N.; Zizak, I.; Feyerherm, R.; Dudzik, E.; Kaskel, S.: In situ monitoring of structural changes during the adsorption on flexible porous coordination polymers by X-ray powder diffraction: Instrumentation and experimental results. Microporous and Mesoporous Materials 188 (2014), p. 190-195
Kojda, D.; Wallacher, D.; Baudoin, S.; Hansen, T.; Huber, P.; Hofmann, T.: Solid phases of spatially nanoconfined oxygen: A neutron scattering study. The Journal of Chemical Physics 140 (2014), p. 024705/1-9
Stoeckel, D.; Wallacher, D.; Zickler, G.A.; Perlich, J.; Tallarek, U.; Smarsly, B.M.: Coherent Analysis of Disordered Mesoporous Adsorbents using Small Angle X-Ray Scattering and Physisorption Experiments. Physical Chemistry Chemical Physics 16 (2014), p. 6583-6592
2013
Campbell, S.J.; Hofmann, M.; Mole, R.A.; Prokes, K.; Wallacher, D.; Wang, J.L.: Magnetic Order in YbMn2Si2 - Neutron Scattering Investigation. Journal of the Korean Physical Society 63 (2013), p. 314-319
Hofmann, T.; Kumar, P.; Enderle, M.; Wallacher, D.: Growth of Highly Oriented Deuterium Crystals in Silicon Nanochannels. Physical Review Letters 110 (2013), p. 065505/1-5
Jalarvo, N.; Casolo, S.; Aliouane, N.; Wallacher, D.; Lovvik, O.M.; Norby, T.: On the Complex Structural Picture of the Ionic Conductor Sr6Ta2O11. The Journal of Physical Chemistry C 117 (2013), p. 9543-9549
Karg, M.; Prévost, S.; Brandt, A.; Wallacher, D.; von Klitzing, R.; Hellweg, T.: Poly-NIPAM Microgels with Different Cross-Linker Densities : Scaling Behavior of the Network Fluctuations in the Vicinity of the Volume Phase Transition. In: Gabriele Sadowski ... [Ed.] : Intelligent hydrogelsCham [u.a.]: Springer, 2013 (Progress in Colloid and Polymer Science ; 140). - ISBN 978-3-319-01682-5 , p. 63-76
Rother, G.; Ilton, E.S.; Wallacher, D.; Hauß, T.; Schaef, H.T.; Qafoku, O.; Rosso, K.M.; Felmy, A.R.; Krukowski, E.G.; Stack, A.G.; Grimm, N.; Bodnar, R.J.: CO2 Sorption to Subsingle Hydration Layer Montmorillonite Clay Studied by Excess Sorption and Neutron Diffraction Measurements. Environmental Science & Technology 47 (2013), p. 205-211
Stehle, R.; Goerigk, G.; Wallacher, D.; Ballauff, M.; Seiffert, S.: Small-angle X-ray scattering in droplet-based microfluidics. Lab on a Chip 13 (2013), p. 1529-1537
2012
Erko, M.; Wallacher, D.; Findenegg, G.H.; Paris, O.: Repeated sorption of water in SBA-15 investigated by means of in situ small-angle x-ray scattering. Journal of Physics: Condensed Matter 24 (2012), p. 284112/1-8
Erko, M.; Wallacher, D.; Hoell, A.; Hauß, T.; Zizak, I.; Paris, O.: Density minimum of confined water at low temperatures: a combined study by small-angle scattering of X-rays and neutrons. Physical Chemistry Chemical Physics 14 (2012), p. 3852-3858
Erko, M.; Wallacher, D.; Paris, O.: Deformation mechanism of nanoporous materials upon water freezing and melting. Applied Physics Letters 101 (2012), p. 181905/1-4
Gruszkiewicz, M.S.; Rother, G.; Wesolowski, D.J.; Cole, D.R.; Wallacher, D.: Direct Measurements of Pore Fluid Density by Vibrating Tube Densimetry. Langmuir 28 (2012), p. 5070-5078
Hofmann, T.; Wallacher, D.; Mayorova, M.; Zorn, R.; Frick, B.; Huber, P.: Molecular dynamics of n-hexane: A quasi-elastic neutron scattering study on the bulk and spatially nanochannel-confined liquid. The Journal of Chemical Physics 136 (2012), p. 124505/1-9
Kalisvaart, W.P.; Luber, E.J.; Poirier, E.; Harrower, C.T.; Teichert, A.; Wallacher, D.; Grimm, N.; Steitz, R.; Fritzsche, H.; Mitlin, D.: Probing the Room Temperature Deuterium Absorption Kinetics in Nanoscale Magnesium Based Hydrogen Storage Multilayers Using Neutron Reflectometry, X-ray Diffraction, and Atomic Force Microscopy. The Journal of Physical Chemistry C 116 (2012), p. 5868-5880
Kandemir, T.; Wallacher, D.; Hansen, T.; Liss, K.-D.; Naumann d'Alnoncourt, R.; Schlögl, R.; Behrens, M.: In situ neutron diffraction under high pressure - Providing an insight into working catalysts. Nuclear Instruments & Methods in Physics Research A 673 (2012), p. 51 - 55
Remhof, A.; Yan, Y.; Friedrichs, O.; Kim, J.W.; Mauron, Ph.; Borgschulte, A.; Wallacher, D.; Buchsteiner, A.; Hoser, A.; Oh, K.H.; Cho, Y.W.; Züttel, A.: Towards room temperature, direct, solvent free synthesis of tetraborohydrides. Journal of Physics: Conference Series 340 (2012), p. 012111/1-8
Rother, G.; Krukowski, E.G.; Wallacher, D.; Grimm, N.; Bodnar, R.J.; Cole, D.R.: Pore size effects on the sorption of supercritical CO2 in mesoporous CPG-10 silica. The Journal of Physical Chemistry C 116 (2012), p. 917-922
Sharifi, M.; Wallacher, D.; Wark, M.: Distribution of functional groups in periodic mesoporous organosilica materials studied by small-angle neutron scattering with in situ adsorption of nitrogen. Beilstein Journal of Nanotechnology 3 (2012), p. 428-437
2011
Demeter, J.; Teichert, A.; Kiefer, K.; Wallacher, D.; Ryll, H.; Menendez, E.; Paramanik, D.; Steitz, R.; Van Haesendonck, C.; Vantomme, A.; Temst, K.: Simultaneous polarized neutron reflectometry and anisotropic magnetoresistance measurements. Review of Scientific Instruments 82 (2011), p. 033902
Hauptvogel, I.M.; Biedermann, R.; Klein, N.; Senkovska, I.; Cadiau, A.; Wallacher, D.; Feyerherm, R.; Kaskel, S.: Flexible and Hydrophobic Zn-Based Metal-Organic Framework. Inorganic Chemistry 50 (2011), p. 8367-8374
Mihalik, M.; Pospisil, J.; Rudajevová, A.; Marti, X.; Wallacher, D.; Hoser, A.; Hofmann, T.; Divis, M.; Sechovský, V.: Structure phase transitions of polymorphic compounds with layered crystal structures: The REIr2Si2 case. Intermetallics 19 (2011), p. 1622 - 1626
Poirier, E.; Harrower, C.T.; Kalisvaart, P.; Bird, A.; Teichert, A.; Wallacher, D.; Grimm, N.; Steitz, R.; Mitlin, D.; Fritzsche, H.: Deuterium absorption in Mg70Al30 thin films with bilayer catalysts: A comparative neutron reflectometry study. Journal of Alloys and Compounds 509 (2011), p. 5466-5471
Sharifi, M.; Marschall, R.; Wilhelm, M.; Wallacher, D.; Wark, M.: Detection of Homogeneous Distribution of Functional Groups in Mesoporous Silica by Small Angle Neutron Scattering and in Situ Adsorption of Nitrogen or Water. Langmuir 27 (2011), p. 5516 - 5522
2010
Erko, M.; Wallacher, D.; Brandt, A.; Paris, O.: In-situ small-angle neutron scattering study of pore filling and pore Emptying in ordered mesoporous silica. Journal of Applied Crystallography 43 (2010), p. 1 - 7
Friedrichs, O.; Kim, J.W.; Remhof, A.; Wallacher, D.; Hoser, A.; Cho, Y.W.; Oh, K.H.; Züttel, A.: Core shell structure for solid gas synthesis of LiBD4. Physical Chemistry Chemical Physics 12 (2010), p. 4600 - 4603
Getzschmann, J.; Senkovska, I.; Wallacher, D.; Tovar, M.; Fairen-Jimenez, D.; Dueren, T.; van Baten, J.M.; Krishna, R.; Kaskel, S.: Methane storage mechanism in the metal-organic framework Cu3(btc)2: An in situ neutron diffraction study. Microporous and Mesoporous Materials 136 (2010), p. 50-58
Kandemir, T.; Wallacher, D.; Tovar, M.; Behrens, M.: In situ Neutron Diffraction Study of a Methanol Synthesis Catalyst under Working Conditions. Zeitschrift für Anorganische und Allgemeine Chemie 636 (2010), p. 2088
Martelli, P.; Remhof, A.; Borgschulte, A.; Mauron, P.; Wallacher, D.; Kemner, E.; Russina, M.; Pendolino, F.; Züttel, A.: BH4- Self-Diffusion in Liquid LiBH4. The Journal of Physical Chemistry A 114 (2010), p. 10117 - 10121
Mascotto, S.; Wallacher, D.; Kuschel, A.; Polarz, S.; Zickler, G.A.; Timmann, A.; Smarsly, B.M.: Adsorption in Periodically Ordered Mesoporous Organosilica Materials Studied by in Situ Small-Angle X-ray Scattering and Small-Angle Neutron Scattering. Langmuir 26 (2010), p. 6583-6592
2009
Friedrich, O.; Kim, J.W.; Remhof, A.; Buchter, F.; Borgschulte, A.; Wallacher, D.; Cho, Y.W.; Fichtner, M.; Oh, K.H.; Züttel, A.: The effect of Al on the hydrogen sorption mechanism of LiBH4. Physical Chemistry Chemical Physics 11 (2009), p. 1515-1520
Gruener, S.; Hofmann, T.; Wallacher, D.; Kityk, A.V.; Huber, P.: Capillary rise of water in hydrophilic nanopores. Physical Review E 79 (2009), p. 067301/1-4
Himsl, D.; Wallacher, D.; Hartmann, M: Improving the Hydrogen-Adsorption Properties of a Hydroxy-Modified MIL-53(Al) Structural Analogue by Lithium Doping. Angewandte Chemie - International Edition 48 (2009), p. 4639-4642
Jung, D.; Paradiso, M.; Wallacher, D.; Brandt, A.; Hartmann, M.: Formation of Cross-Linked Chloroperoxidase Aggregates in the Pores of Mesocellular Foams: Characterization by SANS and Catalytic Properties. ChemSusChem 2 (2009), p. 161-164
Mascotto, S.; Wallacher, D.; Brandt, A.; Hauss, T.; Thommes, M.; Zickler, G.A.; Funari, S.S.; Timmann, A.; Smarsly, B.M.: Analysis of Microporosity in Ordered Mesoporous Hierarchically Structured Silica by Combining Physisorption With in Situ Small-Angle Scattering (SAXS and SANS). Langmuir 25 (2009), p. 12670-12681
Remhof, A.; Friedrichs, O.; Buchter, F.; Mauron, Ph.; Kim, J.W.; Oh, K.H.; Buchsteiner, A.; Wallacher, D.; Züttel, A.: Hydrogen cycling behavior of LiBD4/Al studied by in situ neutron diffraction. Journal of Alloys and Compounds 484 (2009), p. 654-659
2008
Knorr, K.; Huber, P.; Wallacher, D.: Thermodynamic and Structural Investigations of Condensates of Small Molecules in Mesopores. Zeitschrift für Physikalische Chemie 222 (2008), p. 257-285
Remhof, A.; Friedrichs, O.; Buchter, F.; Mauron, Ph.; Züttel, A.; Wallacher, D.: Solid-state synthesis of LiBD4 observed by in situ neutron diffraction. Physical Chemistry Chemical Physics 10 (2008), p. 5859-5862
Wiedenmann, A.; Keiderling, U.; Meissner, M.; Wallacher, D.; Gähler, R.; May, R.P.; Prévost, S.; Klokkenburg, M.; Erné, B.H.; Kohlbrecher, J.: Low-temperature dynamics of magnetic colloids studied by time-resolved small-angle neutron scattering. Physical Review B 77 (2008), p. 184417/1-11
2007
Sel, O.; Brandt, A.; Wallacher, D.; Thommes, M.; Smarsly, B.: Pore hierarchy in mesoporous silicas evidenced by in-situ SANS during nitrogen physisorption. Langmuir 23 (2007), p. 4724-4727