Recommended reading: Bunsen magazine with focus on molecular water research
Water not only has some well-known anomalies, but is still full of surprises. The first issue 2023 of the Bunsen Magazine is dedicated to molecular water research, from the ocean to processes in electrolysis. The issue presents contributions from researchers cooperating within the framework of a European research initiative in the "Centre for Molecular Water Science" (CMWS). A team at HZB presents results from the synchrotron spectroscopy of water. Modern X-ray sources can be used to study molecular and electronic processes in water in detail.
With their report on "Local and collective properties of water", Annette Pietzsch, Robert Seidel and Alexander Föhlisch from HZB describe insights on the nature of water, gained with synchrotron spectroscopy at BESSY II. For example, water, which is normally a perfect insulator, can become metallic under certain conditions.
Other contributions explain the challenges of desalinating seawater, processes in electrolysis or structures in ice on the nanoscale.
These insights help in the design of even better climate models, in environmental research, the design of drugs and vaccines, but also in the development of novel catalysts for green hydrogen or other important technologies.
- Battery research with the HZB X-ray microscopeNew cathode materials are being developed to further increase the capacity of lithium batteries. Multilayer lithium-rich transition metal oxides (LRTMOs) offer particularly high energy density. However, their capacity decreases with each charging cycle due to structural and chemical changes. Using X-ray methods at BESSY II, teams from several Chinese research institutions have now investigated these changes for the first time with highest precision: at the unique X-ray microscope, they were able to observe morphological and structural developments on the nanometre scale and also clarify chemical changes.
- BESSY II: New procedure for better thermoplasticsBio-based thermoplastics are produced from renewable organic materials and can be recycled after use. Their resilience can be improved by blending bio-based thermoplastics with other thermoplastics. However, the interface between the materials in these blends sometimes requires enhancement to achieve optimal properties. A team from the Eindhoven University of Technology in the Netherlands has now investigated at BESSY II how a new process enables thermoplastic blends with a high interfacial strength to be made from two base materials: Images taken at the new nano station of the IRIS beamline showed that nanocrystalline layers form during the process, which increase material performance.
- Hydrogen: Breakthrough in alkaline membrane electrolysersA team from the Technical University of Berlin, HZB, IMTEK (University of Freiburg) and Siemens Energy has developed a highly efficient alkaline membrane electrolyser that approaches the performance of established PEM electrolysers. What makes this achievement remarkable is the use of inexpensive nickel compounds for the anode catalyst, replacing costly and rare iridium. At BESSY II, the team was able to elucidate the catalytic processes in detail using operando measurements, and a theory team (USA, Singapore) provided a consistent molecular description. In Freiburg, prototype cells were built using a new coating process and tested in operation. The results have been published in the prestigious journal Nature Catalysis.