Perovskite solar cells from the slot die coater - a step towards industrial production
The wet coating with a standard ink composition: the wet perovskite thin films (left) has a rib-like structure. The corresponding SEM image (right) of the annealed perovskite film shows inhomogeneities. © HZB
The wet coating with the optimised ink composition (left) is nearly perfectly even. The corresponding SEM image (right) of the annealed perovskite film shows much less inhomogeneities. © HZB
Solar cells made from metal halide perovskites achieve high efficiencies and their production from liquid inks requires only a small amount of energy. A team led by Prof. Dr. Eva Unger at Helmholtz-Zentrum Berlin is investigating the production process. At the X-ray source BESSY II, the group has analyzed the optimal composition of precursor inks for the production of high-quality FAPbI3 perovskite thin films by slot-die coating. The solar cells produced with these inks were tested under real life conditions in the field for a year and scaled up to mini-module size.
Metal halide perovskites are considered to be a particularly low-cost and promising class of materials for next-generation solar modules. Perovskite solar cells can be produced with coating processes using liquid inks made from precursor materials and various solvents. After coating, the solvents evaporate and the perovskites crystallise to form a more or less homogeneous layer.
Options for upscaling
Prof. Dr. Eva Unger's team at Helmholtz-Zentrum Berlin has extensive expertise in solution-based processing methods and is investigating options for upscaling. "Perovskite photovoltaics is the best solution-processable PV technology available," says Eva Unger, "but we are only just beginning to understand how the complex interaction of the solvent components affects the quality of the perovskite layers."
Variations of viscosity
This is because when the halide perovskite layers are coated on large surfaces, unwanted inhomogeneities can occur, for example so-called ribbing structures. "By varying the viscosity of the ink, such effects can be minimised," says Jinzhao Li, who is doing his PhD with Unger. At BESSY II, he has investigated how different solvent combinations affect the crystallisation of the perovskite films. The best p-i-n-FAPbI3 perovskite solar cells thus achieve a certified efficiency of 22.3 % on a laboratory scale. Jinzhao Li also produced mini solar modules (active area of 12.6 cm2) with colleagues from the HySPRINT innovation lab and PVcomB, which achieved efficiencies of around 17 %.
Outdoor test for one year
Dr Carolin Ulbrich's team tested the optimised solar cells at PVcomB’s outdoor test facility for a whole year: In the process, the efficiency remained almost stable in winter and spring, and only dropped in the warmer summer months. "These tests of larger modules under real conditions give us valuable information on degradation mechanisms to then further improve the long-term stability of halide perovskite photovoltaics," says Eva Unger.
- New contact material boosts the efficiency of perovskite solar cellsA newly developed material for the electron contact improves the efficiency of single perovskite solar cells and perovskite/silicon tandem solar cells. The new material is based on a carborane molecule. It offers several advantages over the standard material C60, as shown by the study led by Steve Albrecht’s team. The new material has since been patented and is already commercially available.
- BESSY II: New sample environment allows glimpse into thermocatalytic processesA novel measurement cell allows, for the first time, soft and hard X-ray investigations under high pressures of up to 20 bar and temperatures of up to 400°C. This provides new insights into thermocatalytic processes, such as the Fischer-Tropsch synthesis for producing synthetic fuels. The development of the measurement cell is considered a significant achievement within the Care-O-Sene project.
- Precision interface chemistry pushes perovskite solar cells beyond 26% efficiencyAn international research collaboration has developed a new molecular strategy for controlling one of the most critical interfaces in perovskite solar cells. The resulting solar cells reached a power conversion efficiency of 26.19% in the n i p architecture, together with strong operational stability under prolonged illumination and elevated temperature. The results have been published in the Journal of the American Chemical Society.