Perovskite solar cells from the slot die coater - a step towards industrial production
The wet coating with a standard ink composition: the wet perovskite thin films (left) has a rib-like structure. The corresponding SEM image (right) of the annealed perovskite film shows inhomogeneities. © HZB
The wet coating with the optimised ink composition (left) is nearly perfectly even. The corresponding SEM image (right) of the annealed perovskite film shows much less inhomogeneities. © HZB
Solar cells made from metal halide perovskites achieve high efficiencies and their production from liquid inks requires only a small amount of energy. A team led by Prof. Dr. Eva Unger at Helmholtz-Zentrum Berlin is investigating the production process. At the X-ray source BESSY II, the group has analyzed the optimal composition of precursor inks for the production of high-quality FAPbI3 perovskite thin films by slot-die coating. The solar cells produced with these inks were tested under real life conditions in the field for a year and scaled up to mini-module size.
Metal halide perovskites are considered to be a particularly low-cost and promising class of materials for next-generation solar modules. Perovskite solar cells can be produced with coating processes using liquid inks made from precursor materials and various solvents. After coating, the solvents evaporate and the perovskites crystallise to form a more or less homogeneous layer.
Options for upscaling
Prof. Dr. Eva Unger's team at Helmholtz-Zentrum Berlin has extensive expertise in solution-based processing methods and is investigating options for upscaling. "Perovskite photovoltaics is the best solution-processable PV technology available," says Eva Unger, "but we are only just beginning to understand how the complex interaction of the solvent components affects the quality of the perovskite layers."
Variations of viscosity
This is because when the halide perovskite layers are coated on large surfaces, unwanted inhomogeneities can occur, for example so-called ribbing structures. "By varying the viscosity of the ink, such effects can be minimised," says Jinzhao Li, who is doing his PhD with Unger. At BESSY II, he has investigated how different solvent combinations affect the crystallisation of the perovskite films. The best p-i-n-FAPbI3 perovskite solar cells thus achieve a certified efficiency of 22.3 % on a laboratory scale. Jinzhao Li also produced mini solar modules (active area of 12.6 cm2) with colleagues from the HySPRINT innovation lab and PVcomB, which achieved efficiencies of around 17 %.
Outdoor test for one year
Dr Carolin Ulbrich's team tested the optimised solar cells at PVcomB’s outdoor test facility for a whole year: In the process, the efficiency remained almost stable in winter and spring, and only dropped in the warmer summer months. "These tests of larger modules under real conditions give us valuable information on degradation mechanisms to then further improve the long-term stability of halide perovskite photovoltaics," says Eva Unger.
- Nanosilver as an electrocatalyst for CO₂ reductionVia electrolysis, CO2 can be reduced to CO, a raw material for further chemical products such as fuels. Within the GreenQuest Project, an internation team led by HZB chemist Prashanth Menezes has now systematically investigated catalyst layers made of silver nanoparticles, varying both the size of the particles and their density. The best yield was achieved with nanoparticles with diameters of around 10 nm, which were loosely distributed. Furthermore, they demonstrated how the economic efficiency of the electrochemical cell can be enhanced by integrating an additional chemical reaction at the anode, enabling the simultaneous production of a valuable formic acid, hydrogen, and CO in one device.
- Spin waves inside a nano-oscillator imaged for the first timeFor the first time, researchers have directly imaged the magnetisation dynamics inside a spin Hall nano-oscillator — a nanoscale device that converts direct current into tunable microwave signals and is a promising building block for energy-efficient wireless communication and brain-inspired computing. A Swedish–German team led by the University of Gothenburg and Helmholtz-Zentrum Berlin (HZB) achieved this using time-resolved scanning transmission X-ray microscopy at the MAXYMUS instrument at BESSY II. The results, now published in Advanced Materials, reveal spin-wave features that had escaped previous, indirect measurement techniques.
- Marcel Risch has been appointed Professor at the Freie Universität BerlinMarcel Risch was appointed to a W2-S professorship in the Department of Physics at Freie Universität Berlin in August 2026. His research group has been transformed into the department 'Mechanisms of Sustainable Electrocatalysis'. Risch investigates the fundamental mechanisms of electrocatalytic reactions and, on this basis, develops knowledge- and data-driven strategies to improve electrocatalysts for the sustainable production of hydrogen, fuels and chemicals.