Organic layer adds light particles

The new organic material is able to “add up” low-energy photons (red) to yield higher-energy light (blue), which can then be harvested by the solar cell.

The new organic material is able to “add up” low-energy photons (red) to yield higher-energy light (blue), which can then be harvested by the solar cell. © Y. Y. Cheng/UNSW

Solar cells can only use photons with energies above a specific threshold to generate electricity. A German-Australian research collaboration has now combined solar cells with an organic material which can “add up” low-energy photons to yield higher-energy light, which can then be harvested by the solar cell. In an invited review paper published in the prestigious journal Energy & Environmental Science the scientists give an overview on the fascinating phenomenon of photonic upconversion and report new results: The organic layers show less photo-degradation than suspected and may also be used for other optoelectronics applications.

Every solar cell only uses a small part of the solar spectrum, mainly because it can absorb only light with energies above a material-specific threshold energy. One approach towards circumventing those losses and using more “colors” of the sunlight is photonic upconversion: The solar cell’s backside is coated with a material which can add up low-energy (“red”) photons to yield higher-energy (“blue”) photons which are radiated back towards the solar cell, thus expanding its current harvest. Since 2011, HZB scientists around Prof. Dr. Klaus Lips are collaborating with The University of New South Wales (Sydney, Australia) in investigating novel upconversion materials which have higher efficiencies than the classically employed rare-earth phosphors.

New class of materials

The novel class of organic upconversion materials is based on so-called triplet-triplet annihilation (TTA), and combines strong absorptivity with potentially high quantum yield. The first lab experiments have been published in 2012 in Energy & Environmental Science  (see HZB news report )
“This first report has already been cited over 90 times, which is why we received an invitation to write a review article on this topic” says Dr. Tim Schulze from the Lips team. With an impact factor of >15, Energy & Environmental Science is one of the most distinguished journals in the field.

New data on longevity and efficiency

In the recently published review article, Schulze not only presents a comprehensive overview on the topic but also previously unpublished new data: Together with the Australian partners around Prof. Timothy Schmidt, Schulze has now also investigated the longevity of the TTA molecules under illumination – an extremely critical property for organic materials. The reported results are promising: Even the present not optimized system would last for some years behind a solar cell! “We also have ideas about how to further improve the material”, Schulze says.

At the same time the group reports new record values for the photocurrent enhancement of upconversion-assisted solar cells. “The reached numbers are still far away from a real-world application, but significantly higher than the ones realized with lanthanoid upconversion.”, Schulze explains. And Lips adds: “TTA upconversion is a generic optical technology with potential applications beyond thin-film solar cells. They could also assist photo-electrochemical water splitting or organic LEDs.” The collaboration with Sydney will continue and 2015 will see more joint experiments.

Note: The collaboration, initiated by Lips in 2011 with the help of a DAAD scholarship, has since been greatly intensified: Dr. Tim Schulze was hosted by the Sydney group for one year on an Alexander-von-Humboldt fellowship, advancing materials design and device implementation. At the same time an Australian PhD student stayed at HZB for several weeks on a DAAD scholarship, making use of the BeJEL infrastructure in order to shed light on the interesting spin physics of the TTA systems.

Review-Article 2014: Photochemical upconversion: Present status and prospects for its application to solar energy conversion, Tim Ferdinand Schulze and Timothy W Schmidt, Energy Environ. Sci., 2014

DOI: 10.1039/C4EE02481H

Article 2012: Yuen Yap Cheng, Burkhard Fückel, Rowan W MacQueen, Tony Khoury, Raphaël GCR Clady, Tim F Schulze, NJ Ekins-Daukes, Maxwell J Crossley, Bernd Stannowski, Klaus Lips and Timothy W Schmidt, Energy & Environmental Science 5, 6953-6959 (2012)


arö

  • Copy link

You might also be interested in

  • Optical innovations for solar modules - which are the most promising?
    Science Highlight
    28.03.2025
    Optical innovations for solar modules - which are the most promising?
    In 2023, photovoltaic systems generated more than 5% of the world’s electrical energy and the installed capacity doubles every two to three years. Optical technologies can further increase the efficiency of solar modules and open up new applications, such as coloured solar modules for facades. Now, 27 experts provide a comprehensive overview of the state of research and assess the most promising innovations. The report, which is also of interest to stakeholders in funding and science management, was coordinated by HZB scientists Prof. Christiane Becker and Dr. Klaus Jäger.
  • Catalysis research with the X-ray microscope at BESSY II
    Science Highlight
    27.03.2025
    Catalysis research with the X-ray microscope at BESSY II
    Contrary to what we learned at school, some catalysts do change during the reaction: for example, certain electrocatalysts can change their structure and composition during the reaction when an electric field is applied. The X-ray microscope TXM at BESSY II in Berlin is a unique tool for studying such changes in detail. The results help to develop innovative catalysts for a wide range of applications. One example was recently published in Nature Materials. It involved the synthesis of ammonia from waste nitrates.
  • Samira Aden joins ETIP PV - The European Technology & Innovation Platform for Photovoltaics ESG Working Group
    News
    26.03.2025
    Samira Aden joins ETIP PV - The European Technology & Innovation Platform for Photovoltaics ESG Working Group
    Samira Jama Aden, Architect Design Research, has joined the ETIP PV - The European Technology & Innovation Platform for Photovoltaics working group “Environmental, Social and Governance (ESG)”.