BESSY II: Experimental verification of an exotic quantum phase in Au2Pb
The figure shows the measured energy-momentum relationship for Au2Pb. The linear behavior is evidence for a Dirac semimetal. In addition, a Lifshitz transition is observed: At temperatures 223 K and below, the electrons behave like positively charged particles, whereas at room temperature they behave like negatively charged ones. © HZB
A team of HZB has investigated the electronic structure of Au2Pb at BESSY II by angle-resolved photoemission spectroscopy across a wide temperature range: The results are in accordance with the electronic structure of a three-dimensional topological Dirac semimetal, in agreement with theoretical calculations.
The experimental data unveil some very special features linked to a Lifshitz transition. The study broadens the range of currently known materials exhibiting three-dimensional Dirac phases, and the observed Lifshitz transition demonstrates a viable mechanism to switch the charge carrier type in electric transport without the need for external doping. Moreover, the material becomes interesting as candidate for the realization of a topological superconductor.
The study which includes theory from San Sebastian and synthesis from Princeton was highlighted as Editor's Suggestion in the journal Physical Review Letters.
- Battery research with the HZB X-ray microscopeNew cathode materials are being developed to further increase the capacity of lithium batteries. Multilayer lithium-rich transition metal oxides (LRTMOs) offer particularly high energy density. However, their capacity decreases with each charging cycle due to structural and chemical changes. Using X-ray methods at BESSY II, teams from several Chinese research institutions have now investigated these changes for the first time with highest precision: at the unique X-ray microscope, they were able to observe morphological and structural developments on the nanometre scale and also clarify chemical changes.
- BESSY II: New procedure for better thermoplasticsBio-based thermoplastics are produced from renewable organic materials and can be recycled after use. Their resilience can be improved by blending bio-based thermoplastics with other thermoplastics. However, the interface between the materials in these blends sometimes requires enhancement to achieve optimal properties. A team from the Eindhoven University of Technology in the Netherlands has now investigated at BESSY II how a new process enables thermoplastic blends with a high interfacial strength to be made from two base materials: Images taken at the new nano station of the IRIS beamline showed that nanocrystalline layers form during the process, which increase material performance.
- Hydrogen: Breakthrough in alkaline membrane electrolysersA team from the Technical University of Berlin, HZB, IMTEK (University of Freiburg) and Siemens Energy has developed a highly efficient alkaline membrane electrolyser that approaches the performance of established PEM electrolysers. What makes this achievement remarkable is the use of inexpensive nickel compounds for the anode catalyst, replacing costly and rare iridium. At BESSY II, the team was able to elucidate the catalytic processes in detail using operando measurements, and a theory team (USA, Singapore) provided a consistent molecular description. In Freiburg, prototype cells were built using a new coating process and tested in operation. The results have been published in the prestigious journal Nature Catalysis.