BESSY II: Experimental verification of an exotic quantum phase in Au2Pb
The figure shows the measured energy-momentum relationship for Au2Pb. The linear behavior is evidence for a Dirac semimetal. In addition, a Lifshitz transition is observed: At temperatures 223 K and below, the electrons behave like positively charged particles, whereas at room temperature they behave like negatively charged ones. © HZB
A team of HZB has investigated the electronic structure of Au2Pb at BESSY II by angle-resolved photoemission spectroscopy across a wide temperature range: The results are in accordance with the electronic structure of a three-dimensional topological Dirac semimetal, in agreement with theoretical calculations.
The experimental data unveil some very special features linked to a Lifshitz transition. The study broadens the range of currently known materials exhibiting three-dimensional Dirac phases, and the observed Lifshitz transition demonstrates a viable mechanism to switch the charge carrier type in electric transport without the need for external doping. Moreover, the material becomes interesting as candidate for the realization of a topological superconductor.
The study which includes theory from San Sebastian and synthesis from Princeton was highlighted as Editor's Suggestion in the journal Physical Review Letters.
- Porous Radical Organic framework improves lithium-sulphur batteriesA team led by Prof. Yan Lu, HZB, and Prof. Arne Thomas, Technical University of Berlin, has developed a material that enhances the capacity and stability of lithium-sulphur batteries. The material is based on polymers that form a framework with open pores (known as radical-cationic covalent organic frameworks or COFs). Catalytically accelerated reactions take place in these pores, firmly trapping polysulphides, which would shorten the battery life. Some of the experimental analyses were conducted at the BAMline at BESSY II.
- Metallic nanocatalysts: what really happens during catalysisUsing a combination of spectromicroscopy at BESSY II and microscopic analyses at DESY's NanoLab, a team has gained new insights into the chemical behaviour of nanocatalysts during catalysis. The nanoparticles consisted of a platinum core with a rhodium shell. This configuration allows a better understanding of structural changes in, for example, rhodium-platinum catalysts for emission control. The results show that under typical catalytic conditions, some of the rhodium in the shell can diffuse into the interior of the nanoparticles. However, most of it remains on the surface and oxidises. This process is strongly dependent on the surface orientation of the nanoparticle facets.
- KlarText Prize for Hanna TrzesniowskiThe chemist has been awarded the prestigious KlarText Prize for Science Communication by the Klaus Tschira Foundation.