LiquidJet PES

Soft X-ray photoelectron spectrometer



Gao, S.; Hou, J.; Deng, Z.; Wang, T.; Beyer, S.; Buzanich, A.G.; Richardson, J.J.; Rawal, A.; Seidel, R.; Zulkifli, M.Y.; Li, W.; Bennett, T.D.; Cheetham, A.K.; Liang, K.; Chen, V.: Improving the Acidic Stability of Zeolitic Imidazolate Frameworks by Biofunctional Molecules. , Chem 5 (2019), p. 1597-1608
doi: 10.1016/j.chempr.2019.03.025

Lewis, T.; Winter, B.; Thürmer, S.; Seidel, R.; Stephansen, A.; Freites, J.; Tobias, D.; Hemminger, J.: Molecular Arrangement of a Mixture of Organosulfur Surfactants at the Aqueous Solution-Vapor Interface Studied by Photoelectron Intensity and Angular Distribution Measurements and Molecular Dynamics Simulations. , The Journal of Physical Chemistry C 123 (2019), p. 8160-8170
doi: 10.1021/acs.jpcc.8b08260

Luis, J.L.; Unger, I.; Araujo, T.A.; Rezende, L.R.; Damas, G.; Costa, L.T.; Toledo, K.C. F.; Rocha, T.C.R.; de Brito, A.N.s; Saak, C.-M.; Coutinho, K.; Araki, K.; Björneholm, O.; Brena, B.; Moyses Araujo, C.: X-ray Photoelectron Fingerprints of High-Valence Ruthenium–Oxo Complexes along the Oxidation Reaction Pathway in an Aqueous Environment. , Journal of Physical Chemistry Letters 10 (2019), p. 7636-7643
doi: 10.1021/acs.jpclett.9b02756


Richter, C.; Hollas, D.; Saak, C.-M.; Förstel, M.; Miteva, T.; Mucke, M.; Björneholm, O.; Sisourat, N.; Slavicek, P.; Hergenhahn, U.: Competition between proton transfer and intermolecular Coulombic decay in water. , Nature Communications 9 (2018), p. 4988/1-8
doi: 10.1038/s41467-018-07501-6


Hollas, D.; Pohl, M.N.; Seidel, R.; Aziz, E.F.; Slavicek, P.; Winter, B.: Aqueous Solution Chemistry of Ammonium Cation in the Auger Time Window. , Scientific Reports 7 (2017), p. 756/1-10
doi: 10.1038/s41598-017-00756-x

Pham, T.A.; Govoni, M.; Seidel, R.; Bradforth, S.E.; Schwegler, E.; Galli, G.: Electronic structure of aqueous solutions: Bridging the gap between theory and experiments. , Science Advances 3 (2017), p. 1603210/1-9
doi: 10.1126/sciadv.1603210

Unger, I.; Seidel, R.; Thuermer, S.; Pohl, M.N.; Aziz, E.F.; Cederbaum, L.S.; Muchova, E.; Slavicek, P.; Winter, B.; Kryzhevoi, N.V.: Observation of electron-transfer-mediated decay in aqueous solution. , Nature Chemistry 9 (2017), p. 708–714
doi: 10.1038/nchem.2727

Hans, A.; Ozga, C.; Seidel, R.; Schmidt, P.; Ültzhöffer, T.; Holzapfel, X.; Wenzel, P.; Reiß, P.; Pohl, M.N.; Unger, I.; Aziz, E.F.; Ehresmann, A.; Slavícek, P.; Winter, B.; Knie, A.: Optical Fluorescence Detected from X-ray Irradiated Liquid Water. , The Journal of Physical Chemistry B 121 (2017), p. 2326–2330
doi: 10.1021/acs.jpcb.7b00096


Golnak, R.; Bokarev, S.I.; Seidel, R.; Xiao, J.; Grell, G.; Atak, K.; Unger, I.; Thürmer, S.; Aziz, S.G.; Kühn, O.; Winter, B.; Aziz, E.F.: Joint Analysis of Radiative and Non-Radiative Electronic Relaxation Upon X-ray Irradiation of Transition Metal Aqueous Solutions. , Scientific Reports 6 (2016), p. 25659/1-8
doi: 10.1038/srep24659

Slavicek, P.; Kryzhevoi, N.V.; Aziz, E.F.; Winter, B.: Relaxation Processes in Aqueous Systems upon X-ray Ionization: Entanglement of Electronic and Nuclear Dynamics. , Journal of Physical Chemistry Letters 7 (2016), p. 234-243
doi: 10.1021/acs.jpclett.5b02665

Golnak, R.; Xiao, J.; Atak, K.; Unger, I.; Seidel, R.; Winter, B.; Aziz, E.: Undistorted X-ray Absorption Spectroscopy Using s-Core-Orbital Emissions. , The Journal of Physical Chemistry A 120 (2016), p. 2808-2814
doi: 10.1021/acs.jpca.6b01699

Seidel, R.; Winter, B.; Bradforth, S.E.: Valence Electronic Structure of Aqueous Solutions: Insights from Photoelectron Spectroscopy. , Annual Review of Physical Chemistry 67 (2016), p. 283-305
doi: 10.1146/annurev-physchem-040513-103715

Fransson, T.; Harada, Y.; Kosugi, N.; Besley, N.; Winter, B.; Rehr, J.; Pettersson, L.; Nilsson, A.: X-ray and Electron Spectroscopy of Water. , ACS Chemical Reviews 116 (2016), p. 7551-7569
doi: 10.1021/acs.chemrev.5b00672

Yin, Zhong: X–ray Spectroscopy of Complex Chemical Systems in Liquid Phase. , Göttingen, Georg-August-Universität, Diss., 2016


Kothe, A.; Wilke, M.; Moguilevski, A.; Engel, N.; Winter, B.; Kiyan, I.Yu.; Aziz, E.F.: Charge transfer to solvent dynamics in iodide aqueous solution studied at ionization threshold. , Physical Chemistry Chemical Physics 17 (2015), p. 1918-1924
doi: 10.1039/C4CP02482F

Atak, K.; Golnak, R.; Xiao, J.; Pflüger, M.; Brandenburg, T.; Winter, B.; Aziz, E.F.: Co(III) protoporphyrin IX chloride in solution: spin-state and metal coordination revealed from resonant inelastic X-ray scattering and electronic structure calculations. , Physical Chemistry Chemical Physics 17 (2015), p. 3409-3414
doi: 10.1039/c4cp04703f

Unger, I.; Hollas, D.; Seidel, R.; Thuermer, S.; Aziz, E.F.; Slavicek, P.; Winter, B.: Control of X-ray Induced Electron and Nuclear Dynamics in Ammonia and Glycine Aqueous Solution via Hydrogen Bonding. , The Journal of Physical Chemistry B 119 (2015), p. 10750-10759
doi: 10.1021/acs.jpcb.5b07283

Tentscher, P.R.; Seidel, R.; Winter, B.; Guerard, J.J.; Arey, J.S.: Exploring the Aqueous Vertical Ionization of Organic Molecules by Molecular Simulation and Liquid Microjet Photoelectron Spectroscopy. , The Journal of Physical Chemistry B 119 (2015), p. 238-256
doi: 10.1021/jp508053m

Grell, G.; Bokarev, S.I.; Winter, B.; Seidel, R.; Aziz, E.F.; Aziz, S.G.; Kühn, O.: Multi-reference approach to the calculation of photoelectron spectra including spin-orbit coupling. , The Journal of Chemical Physics 143 (2015), p. 074104/1-9
doi: 10.1063/1.4928511

Schroeder, C.A.; Pluharova, E.; Seidel, E.; Schroeder, W.P.; Faubel, M.; Slavicek, P.; Winter, B.; Jungwirth, P.; Bradforth, S.E.: Oxidation Half-Reaction of Aqueous Nucleosides and Nucleotides via Photoelectron Spectroscopy Augmented by ab Initio Calculations. , Journal of the American Chemical Society 137 (2015), p. 201–209
doi: 10.1021/ja508149e

Kothe, A.; Wilke, M.; Moguilevski, A.; Engel, N.; Winter, B.; Kiyan, I.Yu.; Aziz, E.F.: Reply to the 'Comment on "Charge Transfer to Solvent Dynamics in Iodide Aqueous Solution Studied at Ionization Threshold"'. , Physical Chemistry Chemical Physics 17 (2015), p. 18195-18196
doi: 10.1039/c5cp01804h

Winter, B.: Scientists strike wet gold. , Nature Chemistry 7 (2015), p. 192-194
doi: 10.1038/nchem.2189

Seidel, R.; Atak, K.; Stephan, T.; Aziz, E.F.; Winter, B.: Ti3+ Aqueous Solution: Hybridization and Electronic Relaxation Probed by State-Dependent Electron Spectroscopy. , The Journal of Physical Chemistry B 119 (2015), p. 10607-10615
doi: 10.1021/acs.jpcb.5b03337


Perrine, K.A.; Margarella, A.M.; Van Spyk, M.H.C.; Winter, B.; Faubel, M.; Bluhm, H.; Hemminger, J.C.: Characterization of the Acetonitrile Aqueous Solution/Vapor Interface by Liquid-Jet X-ray Photoelectron Spectroscopy. , The Journal of Physical Chemistry C 118 (2014), p. 29378–29388
doi: 10.1021/jp505947h

Palivec, V.; Pluharova, E.; Unger, I.; Winter, B.; Jungwirth, P.: DNA Lesion Can Facilitate Base Ionization: Vertical Ionization Energies of Aqueous 8-Oxoguanine and its Nucleoside and Nucleotide. , The Journal of Physical Chemistry B 118 (2014), p. 13833–13837
doi: 10.1021/jp5111086

Yepes, D.; Seidel, R.; Winter, B.; Blumberger, J.; Jaque, P.: Photoemission Spectra and Density Functional Theory Calculations of 3d Transition Metal-Aqua Complexes (Ti-Cu) in Aqueous Solution. , The Journal of Physical Chemistry B 118 (2014), p. 6850-6863
doi: 10.1021/jp5012389

Slavicek, P.; Winter, B.; Cederbaum, L.S.; Kryzhevoi, N.V.: Proton-Transfer Mediated Enhancement of Non local Electronic Relaxation Processes in X-ray Irradiated Liquid Water. , Journal of the American Chemical Society 136 (2014), p. 18170-18176
doi: 10.1021/ja5117588

Unger, I.; Thürmer, S.; Hollas, D.; Aziz, E.F.; Winter, B.; Slavicek, P.: Ultrafast Proton and Electron Dynamics in Core-Ionized Hydrated Hydron Peroxide: Photoemission Measurements with Isotopically Substituted Hydrogen Peroxide. , The Journal of Physical Chemistry C 118 (2014), p. 29142–29150
doi: 10.1021/jp504707h


Josefsson, I.; Eriksson, S.K.; Ottosson, N.; Ohrwall, G.; Siegbahn, H.; Hagfeldt, A.; Rensmo, H.; Bjorneholm, O.; Odelius, M.: Collective hydrogen-bond dynamics dictates the electronic structure of aqueous I3-. , Physical Chemistry Chemical Physics 15 (2013), p. 20189-20196
doi: 10.1039/c3cp52866a

Margarella, A.M.; Perrine, K.A.; Lewis, T.; Faubel, M.; Winter, B.; Hemminger, J.C.: Dissociation of Sulfuric Acid in Aqueous Solution: Determination of the Photoelectron Spectral Fingerprints of H2SO4, HSO4, and SO42– in Water. , The Journal of Physical Chemistry C 117 (2013), p. 8131-8137
doi: 10.1021/jp308090k

Brown, MA; Redondo, AB; Sterrer, M; Winter, B; Pacchioni, G; Abbas, Z; van Bokhoven, JA: Measure of Surface Potential at the Aqueous-Oxide Nanoparticle Interface by XPS from a Liquid Microjet. , Nano Letters 13 (2013), p. 5403-5407
doi: 10.1021/nl402957y

Thürmer, S.; Oncak, M.; Ottosson, N.; Seidel, R.; Hergenhahn, U.; Bradforth, S.E.; Slavícek, P.; Winter, B.: On the nature and origin of dicationic, charge-separated species formed in liquid water on X-ray irradiation. , Nature Chemistry 5 (2013), p. 590-596
doi: 10.1038/nchem.1680

Thuermer, S.; Seidel, R.; Faubel, M.; Eberhardt, W.; Hemminger, J.C.; Bradforth, S.E.; Winter, B.: Photoelectron Angular Distributions from Liquid Water: Effects of Electron Scattering. , Physical Review Letters 111 (2013), p. 173005/1-5
doi: 10.1103/PhysRevLett.111.173005

Thurmer, S.; Unger, I.; Petr, S.; Winter, B.: Relaxation of Electronically Excited Hydrogen Peroxide in Liquid Water: Insights from Auger-Electron Emission. , The Journal of Physical Chemistry C 117 (2013), p. 22268–22275
doi: 10.1021/jp401569w

Pluharova, E.; Schroeder, C.; Seidel, R.; Bradforth, S.E.; Winter, B.; Faubel, M.; Slavicek, P.; Jungwirth, P.: Unexpectedly Small Effect of the DNA Environment on Vertical Ionization Energies of Aqueous Nucleobases. , Journal of Physical Chemistry Letters 4 (2013), p. 3766-3769
doi: 10.1021/jz402106h


Pokapanich, W.; Ottosson, N.; Svensson, S.; Öhrwall, G.; Winter, B.; Björneholm, O.: Bond Breaking, Electron Pushing, and Proton Pulling: Active and Passive Roles in the Interaction between Aqueous Ions and Water as Manifested in the O 1s Auger Decay. , The Journal of Physical Chemistry B 116 (2012), p. 3-8
doi: 10.1021/jp2041247

Brown, M.A.; Vila, F.; Sterrer, M.; Thürmer, S.; Winter, B.; Ammann, M.; Rehr, J.J.; van Bokhoven, J.A.: Electronic Structures of Formic Acid (HCOOH) and Formate (HCOO-) in Aqueous Solutions. , Journal of Physical Chemistry Letters 3 (2012), p. 1754-1759
doi: 10.1021/jz300510r

Ghosh, D.; Roy, A.; Seidel, R.; Winter, B.; Bradforth, S.; Krylov, A.I.: First-Principle Protocol for Calculating Ionization Energies and Redox Potentials of Solvated Molecules and Ions: Theory and Application to Aqueous Phenol and Phenolate. , The Journal of Physical Chemistry B 116 (2012), p. 7269-7280
doi: 10.1021/jp301925k

Seidel, R.; Ghadimi, S.; Lange, K.M.; Bonhommeau, S.; Soldatov, M.A.; Golnak, R.; Kothe, A.; Könnecke, R.; Soldatov, A.; Thürmer, S.; Winter, B.; Aziz, E.F.: Origin of dark-channel X-ray fluorescence from transition-metal ions in water. , Journal of the American Chemical Society 134 (2012), p. 1600-1605
doi: 10.1021/ja207931r

Pluharova, E.; Oncak, M.; Seidel, R.; Schroeder, C.; Schroeder, W.; Winter, B.; Bradforth, S.E.; Jungwirth, P.; Slavicek, P.: Transforming Anion Instability into Stability: Contrasting Photoionization of Three Protonation Forms of the Phosphate Ion upon Moving into Water. , The Journal of Physical Chemistry B 116 (2012), p. 13254-13264
doi: 10.1021/jp306348b


Ottosson, N.; Odelius, M.; Spangberg, D.; Pokapanich, W.; Svanqvist, M.; Ohrwall, G.; Winter, B.; Bjorneholm, O.: Cations Strongly Reduce Electron-Hopping Rates in Aqueous Solutions. , Journal of the American Chemical Society 133 (2011), p. 13489-13495
doi: 10.1021/ja204100j

Thürmer, S.; Seidel, R.; Eberhardt, W.; Bradforth, S.E.; Winter, B.: Ultrafast Hybridization Screening in Fe3+ Aqueous Solution. , Journal of the American Chemical Society 133 (2011), p. 12528-12535
doi: 10.1021/ja200268b


Ottosson, N.; Faubel, M.; Bradforth, S.E.; Jungwirth, P.; Winter, B.: Photoelectron spectroscopy of liquid water and aqueous solution: Electron effective attenuation lengths and emission-angle anisotropy. , Journal of Electron Spectroscopy and Related Phenomena 177 (2010), p. 60 - 70
doi: 10.1016/j.elspec.2009.08.007

Ottosson, N.; Heyda, J.; Wernersson, E.; Pokapanich, W.; Svensson, S.; Winter, B.; Ohrwall, G.; Jungwirth, P.; Bjorneholm, O.: The influence of concentration on the molecular surface structure of simple and mixed aqueous electrolytes. , Physical Chemistry Chemical Physics 12 (2010), p. 10693-10700
doi: 10.1039/c0cp00365d

Aziz, Emad F.: The solvation of ions and molecules probed via soft X-ray spectroscopies. , Journal of Electron Spectroscopy and Related Phenomena 177 (2010), p. 168-180
doi: 10.1016/j.elspec.2010.02.009

Panzer, D.; Beck, C.; Hahn, M.; Maul, J.; Schönhense, G.; Decker, H.; Aziz, E.: Water Influences on the Copper Active Site in Hemocyanin. , Journal of Physical Chemistry Letters 1 (2010), p. 1642 - 1647
doi: 10.1021/jz100313q


Ottosson, N.; Vacha, R.; Aziz, E.F.; Pokapanich, W.; Eberhardt, W.; Svensson, S.; Ohrwall, G.; Jungwirth, P.; Bjorneholm, O.; Winter, B.: Large variations in the propensity of aqueous oxychlorine anions for the solution/vapor interface. , The Journal of Chemical Physics 131 (2009), p. 124706/1-7
doi: 10.1063/1.3236805

LiquidJet PES